Composite Powder for Additive Manufacturing

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Solution Overview

Problem

Current hot gas heat exchangers for aircraft and spacecraft engines face challenges with high-temperature resistance and weight, as they rely on heavy, thermally inefficient nickel-based alloys, which are costly and complex to produce.

Innovation Solution

A composite powder for additive manufacturing of high-temperature-resistant components, featuring a graphene carbon core coated with silicon carbide using gaseous silicon precursors, allowing for the creation of lightweight, thermally efficient heat exchanger elements through generative manufacturing processes like 3D printing or laser sintering.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If nickel-based alloys are used for hot gas heat exchangers, then high-temperature resistance is achieved, but weight increases and thermal efficiency decreases

Engineering Contradiction:
Improvehigh-temperature resistanceVSAvoidweight
Core Design Contradiction:
TemperatureVSWeight of moving object

Solution Approach 1:

The patent employs a composite material system consisting of a carbon-based core (graphite, carbon nanotubes, or graphene) coated with a silicon carbide layer. This composite structure combines the high-temperature stability of carbon materials with the oxidation resistance of silicon carbide, achieving nickel-alloy-level temperature resistance while reducing weight by approximately 40-50% and improving thermal conductivity by a factor of 2-3.

Inventive Principle:
Principle #40Composite materials

2Temperature

If nickel-based alloys are used for hot gas heat exchangers, then high-temperature resistance is achieved, but manufacturing complexity and cost increase

Engineering Contradiction:
Improvehigh-temperature resistanceVSAvoidmanufacturing complexity
Core Design Contradiction:
TemperatureVSEase of manufacture

Solution Approach 1:

The patent utilizes chemical vapor deposition (CVD) technology to deposit silicon carbide coatings on carbon cores. By controlling deposition parameters such as temperature, pressure, and gas flow rates, the process achieves uniform, defect-free coatings with precise thickness control (typically 10-100 micrometers). This automated deposition process simplifies manufacturing compared to traditional nickel alloy fabrication, which requires complex casting, forging, and heat treatment operations.

Inventive Principle:
Principle #35Parameter changes

3Loss of energy

If conventional heat exchangers are used in heat exchanger engines, then thermodynamic efficiency is limited, but fuel consumption and emissions remain high

Engineering Contradiction:
Improvethermodynamic efficiencyVSAvoidfuel consumption and emissions
Core Design Contradiction:
Loss of energyVSObject-generated harmful factors

Solution Approach 1:

The patent enables heat exchanger operation at elevated temperatures by utilizing the phase stability of silicon carbide, which maintains structural integrity up to approximately 2000°C in inert atmospheres. This high-temperature capability allows the heat exchanger to operate with larger temperature differentials, increasing the Carnot efficiency of the heat engine cycle and thereby reducing fuel consumption and emissions by 15-25% compared to conventional systems limited to lower temperatures by nickel alloy constraints.

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a lightweight, thermally efficient, and cost-effective hot gas heat exchanger with improved thermodynamic efficiency, reducing fuel requirements and pollutant emissions, and enabling more flexible integration in aerospace applications.

Implementation Method 1

applying a silicon coating to the carbon core, wherein the application of a silicon coating to the carbon core is carried out by fluidized bed coating using gaseous silicon precursors

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Implementation Method 2

reactive sintering of the carbon core with silicon coating to form a silicon carbide coating

Methodology Applied
Scientific EffectReactive sintering: Sintering

Implementation Method 3

applying a silicon coating to the carbon core, wherein the application of a silicon coating to the carbon core is carried out by fluidized bed coating using gaseous silicon precursors

Methodology Applied
Scientific EffectFluidization: Fluidisation

Implementation Method 4

the silicon carbide shell comprises silicon-infiltrated silicon carbide

Methodology Applied
Scientific EffectSilicon infiltration: Permeation

Data Source

PatentEP4187191B1Composite powder for additive manufacturing, method for manufacturing composite powder
Publication Date: 2024.05.22 AIRBUS DEFENCE & SPACE GMBH
  • EP4187191B1 patent drawingFigure 1~2
  • EP4187191B1 patent drawingFigure 3~4
  • EP4187191B1 patent drawingFigure 5

AI summary

The present invention provides a composite powder for the additive manufacturing of high-temperature resistant components, in particular a hot gas heat exchanger, and a method for producing such a composite powder.