Composite Pressure Vessels Using Surface-Modified Nanoparticles

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Solution Overview

Problem

Current pressure vessels made from fiber composites face limitations in achieving greater reductions in weight and improvements in strength without increasing fiber content, as the burst strength is predominantly dominated by fiber properties, neglecting the potential contributions of matrix resins.

Innovation Solution

Incorporating surface-modified nanoparticles into the matrix resin system within the fiber composite pressure vessels, which enhances the burst strength without requiring additional fiber content, allowing for reduced weight and potentially eliminating composite layers while maintaining strength.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If fiber content is increased to improve burst strength, then strength is improved, but weight increases

Engineering Contradiction:
Improveburst strengthVSAvoidweight
Core Design Contradiction:
StrengthVSWeight of moving object

Solution Approach 1:

The patent applies composite materials by incorporating surface-modified nanoparticles into the matrix resin system. This creates a hybrid composite structure where nanoparticles (such as silica, alumina, or titania) are dispersed within the resin matrix that binds the fibers. This composite approach enhances the burst strength of the pressure vessel without requiring additional fiber content, thereby avoiding the weight penalty associated with increasing fiber quantity. The nanoparticles reinforce the matrix resin, which in turn better supports the fiber structure, achieving strength improvement through a multi-phase composite system rather than simply adding more fibers.

Inventive Principle:
Principle #40Composite materials

2Strength

If fiber content is increased to improve burst strength, then strength is improved, but material usage increases

Engineering Contradiction:
Improveburst strengthVSAvoidmaterial usage
Core Design Contradiction:
StrengthVSLoss of substance

Solution Approach 1:

The patent applies parameter changes by modifying the chemical and physical properties of the matrix resin through nanoparticle incorporation. The surface-modified nanoparticles alter the resin system's parameters including viscosity, crosslinking density, and mechanical properties. This enables the existing fiber content to be more effectively utilized, extracting greater strength potential from the same amount of fiber material. The nanoparticle-reinforced matrix creates a more efficient load transfer mechanism to the fibers, improving burst strength without requiring additional fiber material.

Inventive Principle:
Principle #35Parameter changes

3Strength

If traditional matrix resin is used, then manufacturing is simple, but burst strength is limited

Engineering Contradiction:
Improveburst strengthVSAvoidmanufacturing complexity
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent applies the intermediary principle by introducing surface-modified nanoparticles as a mediating component between the matrix resin and the fibers. These nanoparticles act as a bridge that enhances the interaction between the resin matrix and the fiber reinforcement. The surface modification on the nanoparticles (such as silane coupling agents) creates compatible interfaces that improve stress transfer. This intermediary approach systematically enhances burst strength through a well-defined mechanism while maintaining manufacturing processes that are extensions of conventional composite fabrication techniques.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a significant 7% increase in average delivered fiber strength and improved cycle life of pressure vessels, demonstrating the effectiveness of surface-modified nanoparticles in enhancing composite fiber strength and reducing material usage.

Implementation Method 1

A surface-modifying agent is ionically associated with the core

Methodology Applied
Scientific EffectIonic association: Ion Repulsion/Attraction

Data Source

PatentEP2583020B1Composite pressure vessels
Publication Date: 2021.02.17 3M INNOVATIVE PROPERTIES CO
  • EP2583020B1 patent drawingFigure 1~3
  • EP2583020B1 patent drawingFigure 4~5
  • EP2583020B1 patent drawing

AI summary

Pressure vessels formed from fiber composites are described. The fiber composites include fibers impregnated with a resin system containing surface-modified nanoparticles dispersed in a curable matrix resin.