Composite Proppant with Polymeric Carrier for Settling Control

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Solution Overview

Problem

Hydraulic fracturing in the oil and gas industry faces challenges such as proppant embedment, fluid residue blocking pores, inorganic and organic scaling, and poor proppant transport properties, leading to reduced permeability and short-term effectiveness of scale inhibitors.

Innovation Solution

A composite proppant is developed with a polymeric carrier that includes scale inhibitors, featuring a unique shape and composition to slow down settling and provide controlled release of inhibitors, enhancing proppant transport and long-term protection against scaling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If proppant particles are used in hydraulic fracturing, then fracture conductivity is improved, but proppant settles in fracturing fluid due to higher density leading to poor transport properties

Engineering Contradiction:
Improvefracture conductivityVSAvoidproppant settling rate
Core Design Contradiction:
ReliabilityVSSpeed

Solution Approach 1:

The patent attaches polymeric carriers with specific shapes (disks, plates, stripes, spirals, bundles of fibers, fragments of net or film) to proppant particles. These carriers extend the proppant structure into additional spatial dimensions, increasing hydrodynamic radius and resistance to settling while maintaining the proppant's fracture-conductivity function.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Solution Approach 2:

The patent creates composite proppant structures by combining solid proppant particles with polymeric carriers. The composite comprises both the dense proppant core (for conductivity) and the lighter polymeric carrier (for improved transport), resolving the contradiction between density-related settling and conductivity requirements.

Inventive Principle:
Principle #40Composite materials

2Reliability

If scale inhibitors are injected into formation during fracturing treatment, then protection against inorganic and organic scales is provided, but the chemicals are easily washed out during production stage leading to short duration of treatment

Engineering Contradiction:
Improveprotection against scalingVSAvoidduration of inhibitor treatment
Core Design Contradiction:
ReliabilityVSDuration of action of moving object

Solution Approach 1:

The patent incorporates scale inhibitors into the polymeric carrier structure before proppant injection. The inhibitors are pre-positioned within the carrier matrix, ready for controlled release during production, ensuring prolonged protection without requiring repeated injections.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The polymeric carrier provides a sustained release mechanism for scale inhibitors during the production stage. As the polymer degrades or dissolves over time, inhibitors are continuously released, maintaining protective concentrations in the fracture and extending treatment duration far beyond simple injection methods.

Inventive Principle:
Principle #20Continuity of useful action

3Speed

If polymeric carriers with specific shapes are attached to proppant particles, then proppant settling rate decreases and transport is improved, but the structure becomes more complex

Engineering Contradiction:
Improveproppant transport efficiencyVSAvoidproppant structure complexity
Core Design Contradiction:
SpeedVSDevice complexity

Solution Approach 1:

The patent uses thin polymeric carrier structures (disks, plates, stripes, films) that are simple in form but effective in function. These thin-film carriers provide sufficient hydrodynamic resistance to settling while maintaining manufacturability and avoiding excessive structural complexity.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The patent optimizes parameters such as carrier size, shape, and polymeric material selection to achieve the desired balance between settling resistance and structural simplicity. By adjusting these parameters, effective transport is achieved without requiring overly complex multi-component structures.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite proppant improves proppant transport and longevity, maintaining high hydraulic fracture conductivity by delaying inhibitor release, thus extending the period between downhole treatments and increasing hydrocarbon production.

Implementation Method 1

by regulating the shape of proppant particles in such a way as to increase their 'windage' (i. e. hydrodynamic resistance to motion of proppant particles through the fracturing fluid), which results in a lower settling rate of proppant particles in fracturing fluid

Methodology Applied
Scientific EffectHydrodynamic resistance: Drag

Implementation Method 2

the polymeric carrier comprises inclusions of at least one inhibitor for inorganic or organic scales

Methodology Applied
Scientific EffectControlled release: Diffusion

Implementation Method 3

A decrease in proppant settling rate has been addressed in a number of patents and patent applications

Methodology Applied
Scientific EffectDissolution: Solvation

Data Source

PatentUS10221351B2Composite proppant, method for producing a composite proppant and methods of its application
Publication Date: 2019.03.05 SCHLUMBERGER TECH CORP
  • US10221351B2 patent drawing
  • US10221351B2 patent drawing
  • US10221351B2 patent drawing

AI summary

The disclosure relates to the oil and gas industry, in particular, to a composite proppant modified by a polymeric carrier for the purpose of improving transport properties and delayed release of inhibitors from proppant. A composite proppant is provided which comprises at least one solid particle attached to at least one polymeric carrier facilitating a decrease in the composite proppant settling rate, where the polymeric carrier comprises inclusions of at least one inhibitor for inorganic or organic scales. The disclosure also relates to a method for manufacturing of such composite proppant and methods for using the same during hydraulic fracturing of a subterranean formation, and for treatment of organic fossils during downhole production after hydraulic fracturing of subterranean formation.