Composite Resin Particle Dispersion for Tackiness and Storage Stability

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Solution Overview

Problem

Existing composite resin particle dispersions exhibit decreasing tackiness over time and storage stability issues, leading to short shelf life and inventory management challenges in pre-glued paper products.

Innovation Solution

A method involving the polymerization of a (meth)acrylic acid ester compound to form a (meth)acrylic acid ester-based resin, followed by polymerizing a styrene compound and a vinyl monomer in the presence of the (meth)acrylic acid ester-based resin, resulting in composite resin particles with a specific mass ratio and glass transition temperature difference to enhance tackiness and storage stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a (meth)acrylic acid ester compound is polymerized in the presence of a styrene-based resin to form composite resin particles, then the adhesive properties are improved, but the storage stability deteriorates and aggregation occurs over time

Engineering Contradiction:
Improveadhesive propertiesVSAvoidstorage stability
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The patent segments the resin system into distinct components: composite resin particles (containing polymerized (meth)acrylic acid ester compound) and a styrene-based resin that remains unpolymerized in the dispersion. This segmentation prevents aggregation while maintaining adhesive properties, as the composite particles are dispersed in the liquid styrene-based resin medium rather than forming a continuous crosslinked network.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent utilizes glass transition temperature (Tg) as a key parameter to control the system's behavior. The composite resin particles have a Tg of -50°C or lower (providing tackiness), while the styrene-based resin has a Tg of -100°C or lower (providing fluidity). This parameter differentiation allows the system to maintain both adhesive properties and storage stability without aggregation.

Inventive Principle:
Principle #35Parameter changes

2Strength

If the mass ratio of styrene-based resin to (meth)acrylic acid ester-based resin is optimized, then the tackiness in pressure bonding is improved, but the complexity of formulation increases

Engineering Contradiction:
Improvetackiness in pressure bondingVSAvoidformulation complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent establishes specific mass ratio ranges (styrene-based resin to composite resin particles: 90:10 to 10:90, and styrene-based resin to (meth)acrylic acid ester-based resin: 80:20 to 20:80) to optimize tackiness while simplifying formulation. These parameter specifications provide clear guidance for formulation without requiring complex optimization processes.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies local quality by differentiating the functional roles of different resin components: the composite resin particles provide localized adhesive functionality with specific Tg characteristics, while the styrene-based resin provides the continuous phase with different Tg characteristics. This localized functional assignment simplifies the overall formulation approach.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method produces composite resin particles with improved tackiness in pressure bonding and enhanced storage stability, preventing aggregation and maintaining adhesive properties over time.

Implementation Method 1

polymerizing a (meth)acrylic acid ester compound to form a (meth)acrylic acid ester-based resin

Methodology Applied
Scientific EffectPolymerization:

Implementation Method 2

polymerizing a styrene compound and a vinyl monomer other than the styrene compound in the presence of the (meth)acrylic acid ester-based resin to form composite resin particles

Methodology Applied
Scientific EffectPolymerization:

Data Source

PatentUS12570847B2Method for producing composite resin particle dispersion, method for producing pressure-sensitive adhesive, method for producing pressure-responsive resin, method for producing toner for electrostatic charge image development, and composite resin particle dispersion
Publication Date: 2026.03.10 FUJIFILM BUSINESS INNOVATION CORP
  • US12570847B2 patent drawing
  • US12570847B2 patent drawing
  • US12570847B2 patent drawing

AI summary

A method for producing a composite resin particle dispersion includes: polymerizing a (meth)acrylic acid ester compound to form a (meth)acrylic acid ester-based resin; and polymerizing a styrene compound and a vinyl monomer other than the styrene compound in the presence of the (meth)acrylic acid ester-based resin to form composite resin particles containing a styrene-based resin and the (meth)acrylic acid ester-based resin. The mass ratio of the styrene-based resin to the (meth)acrylic acid ester-based resin in the composite resin particles is from 80:20 to 20:80. A difference between the lowest glass transition temperature and the highest glass transition temperature in the composite resin particles is 30° C. or more.