Composite Solid Electrolyte Preventing Self-Discharge

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Solution Overview

Problem

High-temperature batteries face issues with self-discharge at room temperature, limited ion conductivity, and increased internal resistance due to fragile and costly manufacturing processes of solid electrolytes, as well as output limitations from conventional insulating binders.

Innovation Solution

A composite solid electrolyte is developed by incorporating molten salt powder or a molten salt passivation layer, which acts as an electrical insulator at room temperature, combined with solid electrolyte powder, to prevent self-discharge and enhance ion conductivity, stability, and operational efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If solid electrolyte is used to prevent self-discharge, then electrical insulating properties improve, but ion conductivity deteriorates

Engineering Contradiction:
Improveself-discharge preventionVSAvoidion conductivity
Core Design Contradiction:
ReliabilityVSPower

Solution Approach 1:

The patent uses a composite structure combining solid electrolyte particles with molten salt particles. The solid electrolyte provides electrical insulation to prevent self-discharge, while the molten salt phase provides high ion conductivity. This composite material approach resolves the contradiction by integrating two materials with complementary properties into a single functional electrolyte system.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the physical state parameter of the electrolyte by incorporating molten salt particles that melt at operating temperature. At room temperature, the electrolyte remains solid for insulation, but at operating temperature, the molten salt phase provides liquid-like ion conductivity. This parameter change allows the electrolyte to exhibit different properties at different temperatures, resolving the contradiction between insulation and conductivity.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If electrically insulating binder is added to molten salt electrolyte, then operational stability improves, but internal resistance increases

Engineering Contradiction:
Improveoperational stabilityVSAvoidinternal resistance
Core Design Contradiction:
ReliabilityVSPower

Solution Approach 1:

Instead of using conventional electrically insulating binders, the patent employs a composite electrolyte where molten salt particles are suspended in a solid electrolyte matrix. This composite structure provides both operational stability (through the solid matrix) and low internal resistance (through the molten salt phase), eliminating the need for additional insulating binders that would increase resistance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent replaces expensive and performance-limiting insulating binders with a self-contained composite electrolyte system. The molten salt particles themselves serve the dual function of providing ion conductivity and being contained by the solid electrolyte matrix, eliminating the need for separate binder materials and reducing overall system complexity and cost.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Power

If solid electrolyte sintered disk is used to improve ion conductivity, then manufacturing complexity increases

Engineering Contradiction:
Improveion conductivityVSAvoidmanufacturing process complexity
Core Design Contradiction:
PowerVSDevice complexity

Solution Approach 1:

The patent enables the electrolyte to self-organize into a functional composite structure through simple mixing and molding processes. The solid electrolyte particles and molten salt particles naturally form a stable composite where the molten salt is contained within the solid matrix, eliminating the need for complex sintering, hot pressing, or hot isostatic pressing procedures required for traditional solid electrolyte disks.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent changes the manufacturing approach from high-temperature sintering processes to low-temperature mixing and molding. By utilizing the phase transition properties of molten salt, the electrolyte can be processed in a simple mixed-powder state and then activated through heating, dramatically simplifying the manufacturing process while maintaining high ion conductivity.

Inventive Principle:
Principle #35Parameter changes

4Power

If molten salt electrolyte is used for high ion conductivity, then electrical insulation deteriorates

Engineering Contradiction:
Improveion conductivityVSAvoidelectrical insulation
Core Design Contradiction:
PowerVSReliability

Solution Approach 1:

The patent creates a composite electrolyte where molten salt particles (providing high ion conductivity) are suspended within a solid electrolyte matrix (providing electrical insulation). This composite structure allows the system to simultaneously achieve the high ion conductivity of molten salt and the electrical insulation of solid electrolyte, resolving the contradiction between these two opposing properties.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies local quality by assigning different functional properties to different phases within the electrolyte. The molten salt particles provide localized high ion conductivity pathways, while the solid electrolyte matrix provides localized electrical insulation. This spatial differentiation of properties allows the overall system to achieve both high conductivity and good insulation simultaneously.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite solid electrolyte effectively prevents self-discharge, improves ion conductivity and operational stability, reduces manufacturing costs, and maintains battery capacity during long-term storage, while allowing for high-temperature operation without increased internal resistance.

Implementation Method 1

molten salt powder particles having electrical insulating properties at room temperature

Methodology Applied
Scientific EffectElectrical insulation: Electrical Resistance

Implementation Method 2

solid electrolyte powder particles on which surfaces thereof the molten salt powder particles are combined

Methodology Applied
Scientific EffectIon conduction: Conduction (electrical)

Data Source

PatentUS10998583B1Composite solid electrolyte without self-discharge, battery unit cell having same, and method of manufacturing composite solid electrolyte
Publication Date: 2021.05.04 AGENCY FOR DEFENSE DEV
  • US10998583B1 patent drawing
  • US10998583B1 patent drawing
  • US10998583B1 patent drawing

AI summary

A composite solid electrolyte where self-discharge at room temperature is fundamentally prevented by adding a molten salt powder, which is an electric insulator at room temperature, or applying a molten salt passivation layer. The composite solid electrolyte includes: molten salt powder particles having electrical insulating properties at room temperature; and solid electrolyte powder particles on which surfaces thereof the molten salt powder particles are combined.