Composite Thermal Protection Layer Adhesion

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Solution Overview

Problem

High performance composite components face mechanical performance degradation due to polymer matrix softening under high thermal energy, with existing thermal protection methods being costly, cumbersome, or prone to delamination issues.

Innovation Solution

A method involving a composite component with a primary fibre material and a primer layer of alternative fibre material, integrated into the component, followed by a metallic bonding layer and a ceramic or metallic thermal protection layer to enhance adhesion and thermal insulation, reducing the risk of delamination.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If higher Tg resins are used to increase heat resistance, then thermal protection is improved, but composite cost increases

Engineering Contradiction:
Improveglass transition temperatureVSAvoidcomposite cost
Core Design Contradiction:
TemperatureVSQuantity of substance

Solution Approach 1:

The thermal protection system is segmented into multiple functional layers: a primer layer integrated into the composite, a metallic bonding layer, and a ceramic thermal protection layer. This segmentation allows each layer to perform its specific function optimally while using cost-effective materials rather than requiring the entire composite to use expensive high-Tg resins.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses a composite thermal protection system combining organic primer material with inorganic metallic and ceramic layers. This multi-material composite approach provides superior thermal protection compared to using only high-Tg resins, while being more cost-effective than alternative protection methods.

Inventive Principle:
Principle #40Composite materials

2Temperature

If metallic or ceramic protective coatings are adhesively bonded to composite surfaces, then thermal protection is provided, but delamination occurs due to poor bonding

Engineering Contradiction:
Improvethermal protectionVSAvoidadhesion strength
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

A primer layer serves as an intermediary between the composite substrate and the metallic bonding layer. This primer layer is chemically and mechanically compatible with both the composite and the metal, creating strong interfacial bonding and preventing delamination. The primer acts as a mediator that bridges the incompatible surfaces.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The primer layer modifies the surface parameters of the composite, changing its chemical composition and surface energy to improve wettability and adhesion. This parameter change enables strong bonding between the composite and the metallic thermal protection layer.

Inventive Principle:
Principle #35Parameter changes

3Temperature

If a metallic heat shield is spaced apart from the composite surface to provide an air gap, then thermal protection is achieved, but additional space is required

Engineering Contradiction:
Improvethermal protectionVSAvoidspace surrounding composite component
Core Design Contradiction:
TemperatureVSVolume of moving object

Solution Approach 1:

The thermal protection system uses thin film-like layers (primer layer integrated into the composite and thin metallic and ceramic coatings) to provide thermal protection without requiring significant space. This thin-film approach eliminates the need for bulky air gaps while maintaining effective thermal protection.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The primer layer is merged with the composite component during manufacturing, integrating the thermal protection system into the component structure itself. This merging eliminates the need for separate heat shields and additional spacing, as the protection layers become an integral part of the composite component.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Significantly improves adhesion strength between the composite component and thermal protection layers, enhancing mechanical performance and thermal protection while preventing delamination, as demonstrated by increased adhesion testing results.

Implementation Method 1

applying a ceramic thermal protection layer to the bonding surface for insulating the thermal exposure area

Methodology Applied
Scientific EffectThermal insulation: Thermal Insulation

Implementation Method 2

for reflecting external thermal energy

Methodology Applied
Scientific EffectReflection: Reflection

Data Source

PatentEP3285935B1Method of producing thermally protected composite
Publication Date: 2021.07.07 CARBON REVOLUTION LTD
  • EP3285935B1 patent drawingFigure 1~3
  • EP3285935B1 patent drawingFigure 4~5
  • EP3285935B1 patent drawingFigure 6~7

AI summary

A method of producing a composite component (10) having a thermal protection layer (24) including the steps of: providing a composite component (10) with a primary fibre material (12) and with a primer layer (16) of alternative fibre material overlying the primary fibre material (12) at an area of the composite component intended for high thermal exposure, said area defining a thermal exposure area (18); applying a metallic bonding layer (22) to the primer layer (16) of the thermal exposure area (18) to create a bonding surface at the thermal exposure area (18); and applying a ceramic thermal protection layer (24) to the bonding surface for insulating the thermal exposure area (18) and/or for reflecting external thermal energy, the thermal protection layer (24) having a higher melting point than the metallic bonding layer (22).