Composite Z-pin for Delamination Resistance in Polymer Laminates

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Solution Overview

Problem

Conventional Z-pins made of carbon-fibre-reinforced resin perform poorly under mode II delamination due to transverse rupture, while metallic Z-pins fail under mode I due to low surface roughness and thermal expansion coefficient mismatch, leading to inadequate delamination resistance in composite laminates.

Innovation Solution

A Z-pin formed from a composite material with a polymer matrix and fibres aligned along its length, having an elongation at break of at least 2% and tensile strength of at least 5 GPa, with a polymer matrix matching the thermal expansion coefficient of the host composite, enhancing pull-out resistance and preventing premature rupture under both delamination modes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional carbon-fibre-reinforced resin Z-pins are used, then mode I delamination resistance is improved, but mode II delamination resistance deteriorates due to transverse rupture

Engineering Contradiction:
Improvemode I delamination resistanceVSAvoidmode II delamination resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The invention changes the material parameters of the Z-pin by using a polymer matrix with elongation at break ≥10% and tensile strength ≥120 MPa, combined with fibres having elongation ≥2% and tensile strength ≥5 GPa. This parameter change allows the Z-pin to deform and bend under mode II shear loads without rupturing, enabling frictional pull-out mechanism to operate and improve mode II delamination resistance while maintaining mode I resistance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite material structure for the Z-pin consisting of a polymer matrix reinforced with high-elongation fibres (such as aramid or polyethylene fibres). This composite structure combines the high strength of fibres with the ductility of the polymer matrix, creating a Z-pin that can withstand both mode I tensile loads and mode II shear loads without premature rupture, thereby improving reliability under both delamination modes.

Inventive Principle:
Principle #40Composite materials

2Reliability

If metallic Z-pins are used, then mode II delamination resistance is improved, but mode I delamination resistance deteriorates due to low surface roughness and thermal expansion mismatch

Engineering Contradiction:
Improvemode II delamination resistanceVSAvoidmode I delamination resistance
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The invention changes the surface roughness parameter and thermal expansion coefficient parameter of the Z-pin by selecting a polymer matrix composite material whose thermal expansion coefficient matches the host laminate and whose surface develops sufficient roughness through the fibrous structure. This eliminates the thermal expansion mismatch problem and ensures adequate frictional resistance under mode I tensile loads.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a polymer matrix composite for the Z-pin that has a thermal expansion coefficient substantially matching that of the host composite laminate. This homogeneity in thermal expansion properties prevents differential expansion and contraction between the Z-pin and laminate, maintaining intimate contact and frictional resistance under thermal cycling, thereby improving mode I delamination resistance.

Inventive Principle:
Principle #33Homogeneity

3Stability of the object's composition

If metallic Z-pins are used, then ductility is improved, but galvanic corrosion resistance deteriorates

Engineering Contradiction:
ImproveductilityVSAvoidgalvanic corrosion resistance
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The invention replaces the metallic Z-pin with a polymer matrix composite Z-pin that is inherently resistant to galvanic corrosion. Although metals offer ductility, the polymer composite provides sufficient ductility (through fibre-matrix debonding and fibre pull-out mechanisms) while eliminating the galvanic corrosion problem entirely, as polymers are electrochemically inert and do not participate in galvanic cells.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The Z-pin achieves high resistance to frictional pull-out under both mode I and mode II delamination, improving the longevity and reliability of composite laminates by combining the advantages of carbon-fibre and metallic Z-pins while avoiding their respective disadvantages.

Implementation Method 1

a polymer matrix matching the thermal expansion coefficient of the host composite

Methodology Applied
Scientific EffectThermal expansion coefficient matching: Thermal Expansion

Implementation Method 2

most energy dissipated by frictional forces as the Z-pin is pulled out

Methodology Applied
Scientific EffectFriction: Friction

Data Source

PatentUS11840613B2Z-pin for increasing delamination resistance
Publication Date: 2023.12.12 ROLLS ROYCE PLC
  • US11840613B2 patent drawing
  • US11840613B2 patent drawing
  • US11840613B2 patent drawing

AI summary

A Z-pin for increasing a delamination resistance of continuous fibre-reinforced polymer composites, formed of a composite material including a polymer matrix, and a plurality of fibres embedded in the polymer matrix and aligned along the length direction of Z-pin, the fibres having an elongation at break of at least 2% and a tensile strength of at least 5 GPa, the polymer matrix having an elongation at break equal to or greater than the elongation at break of the fibres, and a tensile strength of at least 120 MPa.