Compressed Hydrogen Filling With Latent Heat Buffer Cooling

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Solution Overview

Problem

Existing hydrogen filling systems face challenges in providing high availability and controllable cooling power while minimizing capital costs, particularly due to peak power demands and significant capital costs associated with high-powered chillers and cryogenic storage methods.

Innovation Solution

A system utilizing a latent heat storage medium in the form of a buffer medium that undergoes a solid-liquid phase transition, decoupling the cooling of hydrogen from the cooling of the buffer medium, allowing for continuous cooling with low-power refrigeration and maintaining a consistent hydrogen temperature during filling operations.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If high-powered chillers are used to meet peak cooling demand during hydrogen filling, then the hydrogen temperature can be controlled within specification, but capital costs increase significantly

Engineering Contradiction:
Improvehydrogen temperature controlVSAvoidcapital costs
Core Design Contradiction:
TemperatureVSEase of manufacture

Solution Approach 1:

The buffer medium is pre-cooled to a temperature below the required hydrogen filling temperature before the filling operation begins. This preliminary cooling action stores thermal energy in the buffer medium, which is then available to meet the peak cooling demand during filling without requiring oversized chillers.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

A buffer medium is introduced as an intermediary thermal storage component between the chiller and the hydrogen stream. This buffer medium absorbs and releases thermal energy, decoupling the peak power demand from the continuous cooling requirement, thereby allowing the use of smaller, more cost-effective chillers.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Temperature

If cryogenic liquid hydrogen storage is used to provide cooling, then the target temperature can be achieved, but evaporation losses occur during idle periods

Engineering Contradiction:
Improvehydrogen temperatureVSAvoidevaporation losses
Core Design Contradiction:
TemperatureVSLoss of substance

Solution Approach 1:

The system changes the temperature parameter of the buffer medium dynamically - cooling it below the target temperature before filling operations and allowing it to warm up during idle periods. This avoids the continuous evaporation losses associated with storing cryogenic liquid hydrogen at fixed low temperatures.

Inventive Principle:
Principle #35Parameter changes

3Temperature

If the buffer medium is continuously cooled to maintain hydrogen temperature, then consistent cooling is achieved, but power consumption increases

Engineering Contradiction:
Improvehydrogen temperature consistencyVSAvoidrefrigeration power
Core Design Contradiction:
TemperatureVSUse of energy by moving object

Solution Approach 1:

Instead of continuous cooling, the buffer medium is cooled periodically before filling operations and then allows natural warming during idle periods. This periodic action pattern reduces the cumulative power consumption while maintaining temperature consistency during the critical filling operations.

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system ensures uniform cooling of hydrogen to a specified temperature range, preventing undershooting, and reduces capital costs by using low-power refrigeration, suitable for various applications including motor vehicles and logistics sites.

Implementation Method 1

a buffer medium (17) which acts as a latent heat storage medium and is in thermal connection at a first heat exchanger surface (18) with at least one substream (12) of the hydrogen (2) to be supplied to the container (10) during a filling operation

Methodology Applied
Scientific EffectPhase transition: Phase Change

Implementation Method 2

buffer medium (17) which acts as a latent heat storage medium

Methodology Applied
Scientific EffectLatent heat storage: Latent Heat

Implementation Method 3

at a first heat exchanger surface (18) with at least one substream (12) of the hydrogen (2) to be supplied to the container (10)

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 4

at a second heat exchanger surface (19) with a refrigeration source (20), wherein, at the second heat exchanger surface (19), the buffer medium (17) is cooled to a temperature below a required temperature of the hydrogen (2) to be supplied to the container (10)

Methodology Applied
Scientific EffectRefrigeration: Cooling

Implementation Method 5

the pressure increase in the tank and the negative Joule-Thomson coefficient in the relevant state range leads to a marked warming of the hydrogen in the container

Methodology Applied
Scientific EffectJoule-Thomson effect: Joule-Thomson Effect

Data Source

PatentUS20250216031A1Device and method for filling a container with compressed gaseous hydrogen
Publication Date: 2025.07.03 MESSER SE & CO KGAA
  • US20250216031A1 patent drawing
  • US20250216031A1 patent drawing

AI summary

A device for filling a container, in particular a vehicle tank, with compressed gaseous hydrogen includes a gas supply system for providing compressed gaseous hydrogen, a connection mechanism for producing a fluidic connection to a container to be filled, and a cooling device for cooling the hydrogen to be supplied to the container. The cooling device includes a cooling unit for cooling the hydrogen. The cooling device has a buffering medium which functions as a latent heat accumulator and which is thermally connected to the gaseous hydrogen to be supplied to the container on a first heat exchanger surface and to the cold source on a second heat exchanger surface.