Compressed Hydrogen Storage Compacts with Polymer Binder

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Solution Overview

Problem

Existing hydrogen storage devices face challenges in meeting international standards with high production costs and complexity, particularly in aligning hydrogen-storing materials with container shapes, which affects efficiency and stability during hydrogen storage and release cycles.

Innovation Solution

A hydrogen storage device comprising bulk material made of compressed compacts with a hydrogen-storing material and a polymer binder, allowing for flexible container shapes and interstitial compensation for volume changes during hydrogen absorption and release, using polymers like EVA, PMMA, and EEAMA for enhanced stability and adhesion, and potentially incorporating a compressible third material for volume expansion compensation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If hydrogen-storing material is aligned with container shape according to international standards, then device compliance and structural stability are improved, but production cost and manufacturing complexity increase

Engineering Contradiction:
Improvedevice compliance and structural stabilityVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The hydrogen-storing material is divided into numerous small compacts (each containing pulverulent first material and binder) that are distributed as bulk material throughout the container. This segmentation allows the material to adapt to any container shape without requiring precise alignment, thereby reducing manufacturing complexity while maintaining structural stability through the distributed compact structure.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention changes the physical state and arrangement parameters of the hydrogen-storing material from fixed-shaped blocks to loose bulk compacts with variable positioning. This parameter change enables the material to conform to different container geometries without precise alignment, simplifying manufacturing while ensuring compliance through adequate hydrogen storage capacity distribution.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If hydrogen-storing material is compressed into fixed shapes to meet container specifications, then device compliance is improved, but production cost increases

Engineering Contradiction:
Improvedevice complianceVSAvoidproduction cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The bulk compact material serves multiple functions simultaneously: it complies with container volume requirements, adapts to various container shapes, simplifies manufacturing procedures, and maintains hydrogen storage capacity. This universal approach eliminates the need for expensive custom-shaped components while ensuring device compliance through proper bulk material placement.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Adaptability or versatility

If pulverulent hydrogen-storing material is used without binder, then material flexibility is improved, but particle separation and stability during hydrogen cycles deteriorate

Engineering Contradiction:
Improvematerial flexibilityVSAvoidparticle separation and stability
Core Design Contradiction:
Adaptability or versatilityVSStability of the object's composition

Solution Approach 1:

The invention creates a composite material system where pulverulent hydrogen-storing first material is combined with binder second material in specific proportions. This composite structure maintains the flexibility and hydrogen storage capacity of the pulverulent material while the binder provides particle cohesion and structural stability during hydrogen absorption and release cycles, preventing particle separation.

Inventive Principle:
Principle #40Composite materials

4Quantity of substance

If compacts are compressed at high pressure to increase density, then packing density is improved, but manufacturing complexity and energy consumption increase

Engineering Contradiction:
Improvepacking densityVSAvoidmanufacturing complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The invention applies compression pressure sufficient to achieve adequate packing density for hydrogen storage, but not excessive pressure that would create manufacturing complexity. The compacts are compressed to a degree that ensures high packing density (at least 60% of container volume) while maintaining simplicity in the compression process and equipment requirements.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables cost-effective production of hydrogen storage devices with high stability over multiple cycles, maintaining hydrogen storage capacity and preventing particle separation, while ensuring thermal and mechanical stability, achieving a packing density of at least 60% and supporting efficient hydrogen absorption and release kinetics.

Implementation Method 1

a second material as binder for the first material that was in pulverulent form before the production by compression

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

Interstices are formed here between the compacts, which, in the course of intercalation and release of hydrogen, are variable in relation to their size to compensate for the change in size of the compacts

Methodology Applied
Scientific EffectElastic deformation: Elasticity

Implementation Method 3

The individual layers of the hydrogen storage elements are aligned relative to one another and functionally connected to one another, for example for conduction of heat

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Data Source

PatentUS11988334B2Hydrogen storage device and a method for producing a hydrogen storage device
Publication Date: 2024.05.21 GKN HYDROGEN GMBH
  • US11988334B2 patent drawing
  • US11988334B2 patent drawing
  • US11988334B2 patent drawing

AI summary

A hydrogen storage device at least comprising a container with a first volume. A bulk material is arranged in the container, the bulk material comprising at least a plurality of pellets produced by a pressing method. Each pellet comprising at least a first material capable of storing hydrogen and a second material as binder for the first material provided in powder form prior to production by way of a pressing method.