Compressible Epoxy Zonal Isolation Sealant for Expandable Tubing

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Solution Overview

Problem

Conventional zonal isolation sealants lack compressibility and resilience, preventing the expansion of expandable tubing without fracturing the system, as they harden before the tubing can be expanded, leading to incomplete sealing and fluid migration between zones.

Innovation Solution

A compressible and resilient epoxy zonal isolation composition that includes epoxy resins and hardening agents, capable of maintaining seal integrity during and after expansion, allowing for the expansion of tubing before, during, or after curing, with specific formulations for different temperature ranges.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional sealants are used for zonal isolation, then zonal isolation is achieved, but the sealant lacks compressibility and prevents expansion of expandable tubing

Engineering Contradiction:
Improvezonal isolationVSAvoidcompressibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent modifies the chemical composition parameters of the sealant by incorporating elastomeric polymers (such as polyethylene glycol, polypropylene glycol, or silicone oils) in specific concentrations (5-50 wt%) alongside epoxy resins and hardening agents. This parameter change transforms the sealant from a rigid, non-compressible conventional formulation to a compliant, compressible formulation that can accommodate expandable tubing expansion while maintaining zonal isolation integrity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite sealant material by combining epoxy resins (providing strength and adhesion), hardening agents (providing structural integrity), and elastomeric polymers (providing compressibility and resilience). This composite formulation achieves a balance between rigidity for isolation and flexibility for tubing expansion, resolving the contradiction between reliable zonal isolation and adaptability to expandable tubing.

Inventive Principle:
Principle #40Composite materials

2Loss of time

If conventional sealants harden quickly, then setting time is reduced, but expandable tubing cannot be expanded after setting

Engineering Contradiction:
Improvesetting timeVSAvoidexpandability window
Core Design Contradiction:
Loss of timeVSAdaptability or versatility

Solution Approach 1:

The patent introduces dynamic properties to the sealant system by using elastomeric polymers that provide time-dependent compliance. The sealant maintains a plastic or semi-plastic state during the expansion window, allowing tubing expansion, then progressively develops full strength and rigidity for long-term isolation. This dynamic behavior extends the effective expandability window without significantly increasing overall setting time.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The elastomeric polymer components act as a cushioning mechanism that absorbs expansion forces before the sealant fully hardens. This beforehand cushioning allows the tubing to be expanded during the setting process without fracturing the sealant, effectively extending the operational window for tubing expansion while maintaining efficient setting characteristics.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

3Reliability

If conventional sealants are used, then zonal isolation is provided, but the sealant is too hard and causes system fracturing during tubing expansion

Engineering Contradiction:
Improvezonal isolationVSAvoidhardness
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent changes the mechanical property parameters of the sealant by incorporating elastomeric polymers that reduce hardness and increase elongation at break. The formulation achieves optimal parameter balance where the sealant maintains sufficient compressive strength for zonal isolation (typically 500-5000 psi compressive strength) while reducing Shore hardness to a range that allows tubing expansion without fracturing (e.g., Shore A 40-70 range).

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The composite formulation combines the high strength and adhesion properties of epoxy resins with the high elongation and compliance properties of elastomeric polymers. This composite material achieves a synergistic effect where the epoxy matrix provides structural integrity for isolation while the elastomeric phase provides ductility and fracture resistance during tubing expansion operations.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition ensures at least 75% to 95% retention of seal integrity after compression, enabling effective zonal isolation and preventing fluid migration, while allowing for the expansion of tubing without loss of seal integrity, thus providing long-term isolation.

Implementation Method 1

An epoxy zonal isolation composition including one epoxy resin or a plurality of epoxy resins and one hardening agent or a plurality of hardening agents where the composition cures to form a cured epoxy zonal isolation composition

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 2

having sufficient compressibility and/or resilience properties to permit compression of the composition without substantial loss in seal integrity or zonal isolation

Methodology Applied
Scientific EffectElasticity: Elasticity

Data Source

PatentUS10301526B2Resin sealant for zonal isolation and methods for making and using same
Publication Date: 2019.05.28 WEATHERFORD TECHNOLOGY HOLDINGS LLC
  • US10301526B2 patent drawing
  • US10301526B2 patent drawing
  • US10301526B2 patent drawing

AI summary

Epoxy-based zonal isolation compositions are capable of being adjusted by varying the epoxy-based compositions for isolating zones in borehole of oil and gas wells under high-temperature, mid-temperature and low-temperature conditions.