Condensed-Cyclic Blue Dopant for OLED Thermal Stability

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Solution Overview

Problem

Current organic light-emitting diodes (OLEDs) face limitations in achieving optimal performance in terms of driving voltage, efficiency, brightness, and lifetime due to the lack of materials with high thermal resistance and suitable emission properties.

Innovation Solution

A condensed-cyclic compound with a novel structure, represented by Formula 1, is introduced, which is used in the organic layer of OLEDs, enhancing thermal resistance and luminous properties, and acting as a blue dopant to improve efficiency, brightness, and color purity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic materials are used in OLEDs, then the device structure is simple and manufacturing is easier, but the thermal resistance is insufficient and performance (driving voltage, efficiency, brightness, lifetime) cannot be optimized

Engineering Contradiction:
ImproveOLED performance (driving voltage, efficiency, brightness, lifetime)VSAvoidthermal resistance
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent employs composite materials by integrating the condensed-cyclic compound (Formula 1) with other organic materials in the OLED structure. This compound combines aromatic linking groups with specific substituent patterns that provide both high thermal resistance and optimized electrical properties, achieving superior thermal stability while maintaining appropriate driving voltage and efficiency characteristics.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies parameter changes by systematically varying the substituent groups (R1-R6, Ar1-Ar6) and their positions in the condensed-cyclic compound structure. By adjusting these molecular parameters, the invention optimizes the balance between thermal resistance, driving voltage, efficiency, and lifetime properties of the OLED material.

Inventive Principle:
Principle #35Parameter changes

2Temperature

If materials with high thermal resistance are used to improve OLED performance, then thermal stability is enhanced, but the emission properties and efficiency may be compromised

Engineering Contradiction:
Improvethermal resistanceVSAvoidemission properties and efficiency
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent applies local quality by designing specific regions within the condensed-cyclic compound molecule to fulfill different functions. The core condensed-cyclic structure (Formula 1) provides thermal resistance, while strategically placed substituent groups (R1-R6) and aromatic linking groups (Ar1-Ar6) are optimized to maintain emission properties and efficiency, ensuring each part of the molecule contributes to the overall performance without compromising other properties.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the condensed-cyclic compound results in OLEDs with improved driving voltage, high efficiency, high luminance, excellent external quantum efficiency, and extended lifetime, while maintaining high thermal resistance to Joule's heat.

Implementation Method 1

When a voltage is applied between the anode and the cathode, holes injected from the anode move to the EML via the HTL, and electrons injected from the cathode move to the EML via the ETL. The holes and electrons recombine in the EML to generate excitons. When the excitons drop from an excited state to a ground state, light is emitted.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 2

maintaining high thermal resistance to Joule's heat

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Data Source

PatentUS9653689B2Condensed-cyclic compound and organic light-emitting diode including the same
Publication Date: 2017.05.16 SAMSUNG DISPLAY CO LTD
  • US9653689B2 patent drawing
  • US9653689B2 patent drawing
  • US9653689B2 patent drawing

AI summary

A condensed-cyclic compound represented by Formula 1 below, and an organic light-emitting diode including the condensed-cyclic compound.wherein R1 through R6, Ar5 and Ar6, and X1 through X10 are defined as in the specification.