Condensed Cyclic Compound for OLED Efficiency and Lifespan

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Solution Overview

Problem

Current organic light-emitting devices face limitations in achieving high efficiency and long lifespan due to challenges in material stability and charge transport capabilities.

Innovation Solution

A condensed cyclic compound represented by Formula 1 is introduced, which can be used in the organic light-emitting device's emission layer or electron transport region, enhancing heat resistance, stability, and charge transport properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of stationary object

If conventional organic light-emitting device materials are used, then device structure is simple and manufacturing is easier, but heat resistance and lifespan are insufficient

Engineering Contradiction:
Improvedevice lifespanVSAvoidmaterial structure complexity
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent employs composite materials by integrating the condensed cyclic compound (Formula 1) with specific substituents (L1, A1, R1-R12) to create a multi-functional material system. This composite structure combines the core condensed cyclic framework with various functional groups that collectively provide enhanced heat resistance, charge transport capability, and device stability, thereby extending lifespan while managing structural complexity through systematic molecular design

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional organic light-emitting device materials are used, then manufacturing process is simpler, but charge transport capability and efficiency are limited

Engineering Contradiction:
Improvedevice efficiencyVSAvoidmaterial synthesis difficulty
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent applies local quality by introducing specific functional groups (L1 linking groups, A1 substituents, and R1-R12 terminal groups) at different positions of the condensed cyclic core structure. Each local region of the molecule is optimized for specific functions: the core provides structural stability and heat resistance, L1 groups enable charge transport, A1 groups modulate electronic properties, and R1-R12 groups tune solubility and processing characteristics. This localized functional optimization achieves high device efficiency while maintaining reasonable manufacturability

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent utilizes parameter changes by systematically varying the chemical structure parameters of the condensed cyclic compound, including different L1 linking groups (Formula 2-10), A1 substituents (Formula 11-20), and R1-R12 terminal groups (Formula 21-30). By adjusting these molecular parameters, the material properties such as HOMO/LUMO energy levels, charge mobility, and thermal stability can be optimized to achieve high device efficiency while balancing synthesis complexity

Inventive Principle:
Principle #35Parameter changes

3Reliability

If materials with better heat resistance are used, then device lifespan increases, but charge transport capability may be compromised

Engineering Contradiction:
Improvematerial stabilityVSAvoidcharge transport limitation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The condensed cyclic compound of Formula (1) achieves multi-functionality by combining multiple capabilities within a single molecular structure. The core condensed cyclic framework provides exceptional heat resistance and structural stability, while the integrated L1 linking groups, A1 substituents, and R1-R12 terminal groups simultaneously provide charge transport pathways and appropriate energy level alignment. This universal design ensures that heat resistance and charge transport capability work synergistically rather than traded off against each other, enhancing both reliability and preventing charge transport limitations

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the condensed cyclic compound improves the efficiency and extends the lifespan of organic light-emitting devices by providing excellent heat resistance and charge transport capabilities.

Implementation Method 1

Holes injected from the first electrode, for example, are transported to the emission layer through the hole transport region, and electrons injected from the second electrode, for example, are transported to the emission layer through the electron transport region

Methodology Applied
Scientific EffectCharge transport: Conduction (electrical)

Implementation Method 2

The use of the condensed cyclic compound improves the efficiency and extends the lifespan of organic light-emitting devices by providing excellent heat resistance and charge transport capabilities

Methodology Applied
Scientific EffectHeat resistance: Thermal Insulation

Implementation Method 3

Carriers, such as the holes and electrons, can then recombine in the emission layer to generate excitons. When the excitons drop from an excited state to a ground state, light is emitted

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9905781B2Condensed cyclic compound and organic light-emitting device including the same
Publication Date: 2018.02.27 SAMSUNG DISPLAY CO LTD
  • US9905781B2 patent drawing
  • US9905781B2 patent drawing
  • US9905781B2 patent drawing

AI summary

An organic light-emitting device includes: a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer; wherein the organic layer includes a condensed cyclic compound of Formula 1:The organic light-emitting device including the condensed cyclic compound may exhibit low driving voltage, high efficiency, high luminance, and long lifespan characteristics.