Condensed Cyclic Compound Host for OLED Efficiency and Lifespan

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Solution Overview

Problem

Organic light-emitting devices (OLEDs) face challenges in achieving low driving voltage, high efficiency, and long lifespan while maintaining high brightness.

Innovation Solution

A novel condensed cyclic compound represented by Formula 1 is integrated into the organic light-emitting device, specifically in the emission layer, where it acts as a host, enhancing the device's efficiency and lifespan by controlling the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) levels.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If conventional organic light-emitting devices are used, then basic light emission is achieved, but driving voltage is high and efficiency is low

Engineering Contradiction:
Improvedriving voltageVSAvoiddevice efficiency
Core Design Contradiction:
PowerVSReliability

Solution Approach 1:

The patent modifies the molecular orbital parameters (HOMO and LUMO levels) of the host material by designing specific condensed cyclic compound structures with particular substituents and heteroatoms, thereby optimizing the energy levels to reduce driving voltage while improving efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite emission layers by combining the novel condensed cyclic compound as host material with phosphorescent dopants, forming a synergistic system that simultaneously achieves low driving voltage and high efficiency through complementary material properties

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If conventional OLED materials are used, then light emission is achieved, but lifespan is limited

Engineering Contradiction:
Improvedevice lifespanVSAvoidoverall device performance
Core Design Contradiction:
Duration of action of stationary objectVSReliability

Solution Approach 1:

The patent optimizes the chemical stability parameters of the host material by incorporating nitrogen-containing heterocyclic structures and specific substituents that resist degradation, thereby extending device lifespan while maintaining performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses organic compounds that can be deposited as thin films, replacing less stable conventional materials with more stable condensed cyclic structures that have superior long-term durability characteristics

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Illumination intensity

If emission layer materials are optimized for brightness, then high brightness is achieved, but driving voltage increases

Engineering Contradiction:
ImprovebrightnessVSAvoiddriving voltage
Core Design Contradiction:
Illumination intensityVSPower

Solution Approach 1:

The patent precisely adjusts the HOMO-LUMO energy gap and molecular orbital levels of the host material to match the phosphorescent dopant, enabling high brightness through efficient energy transfer while maintaining low driving voltage through optimized energy level alignment

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The condensed cyclic compound acts as an intermediary host material that facilitates efficient energy transfer from the electrical excitation to the phosphorescent dopant, enabling high brightness while reducing the voltage required compared to direct electroluminescence

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the condensed cyclic compound in the OLED results in a device with low driving voltage, high efficiency, and long lifespan, along with high brightness, particularly in green emission layers utilizing phosphorescent dopants.

Implementation Method 1

particularly in green emission layers utilizing phosphorescent dopants

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Implementation Method 2

Carriers, such as holes and electrons, are recombined in the emission layer to produce excitons. These excitons change from an excited state to a ground state, thereby generating light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11050027B2Condensed cyclic compound and organic light-emitting device including the same
Publication Date: 2021.06.29 SAMSUNG ELECTRONICS CO LTD
  • US11050027B2 patent drawing
  • US11050027B2 patent drawing
  • US11050027B2 patent drawing

AI summary

A condensed cyclic compound represented by Formula 1wherein in Formula 1, groups X1 to X8, L11, L12, R11, R12 and variables a11, a12, b11, b12 are described in the specification.