Condensed Cyclic Compound for OLED Hole Transfer

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Solution Overview

Problem

Current organic light-emitting devices face limitations in achieving high efficiency, low voltage, high brightness, and long lifespan due to inadequate hole transfer characteristics and energy transfer efficiency.

Innovation Solution

A novel condensed cyclic compound represented by Formula 1 is introduced, which serves as a fluorescent dopant and enhances hole transfer characteristics, included in the organic light-emitting device's emission layer or hole transport region, facilitating energy transfer and improving device performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic light-emitting devices are used, then device structure is simple, but hole transfer characteristics are insufficient and energy transfer efficiency is low

Engineering Contradiction:
Improvehole transfer characteristicsVSAvoiddevice structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent introduces a host-guest system where the host compound acts as an intermediary to facilitate energy transfer from the guest dopant to achieve efficient light emission. The host compound with specific HOMO/LUMO energy levels mediates the charge transport and energy transfer processes, resolving the contradiction between maintaining simple device structure and achieving good hole transfer characteristics.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent optimizes the energy level parameters (HOMO and LUMO values) of the host and guest compounds to achieve efficient charge injection and energy transfer. By carefully selecting compounds with appropriate energy level alignments, the device achieves improved hole transfer characteristics without requiring complex structural modifications.

Inventive Principle:
Principle #35Parameter changes

2Loss of energy

If conventional organic light-emitting devices are used, then manufacturing process is simple, but energy transfer efficiency is low

Engineering Contradiction:
Improveenergy transfer efficiencyVSAvoidmanufacturing process
Core Design Contradiction:
Loss of energyVSEase of manufacture

Solution Approach 1:

The patent achieves high energy transfer efficiency by optimizing the energy level parameters of the host-guest system. The guest compound with higher triplet energy level than the host enables efficient energy transfer while maintaining simple manufacturing processes using conventional vacuum deposition techniques.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite host-guest material system where the guest dopant (e.g., Ir(ppy)3 for phosphorescent or fluorescent compounds) is dispersed in the host matrix. This composite approach enables efficient energy transfer and improved device performance while using standard manufacturing processes.

Inventive Principle:
Principle #40Composite materials

3Illumination intensity

If conventional organic light-emitting devices are used, then device structure is simple, but brightness and efficiency are limited

Engineering Contradiction:
ImprovebrightnessVSAvoiddevice structure
Core Design Contradiction:
Illumination intensityVSDevice complexity

Solution Approach 1:

The host compound serves as an intermediary that facilitates efficient energy transfer to the guest dopant, enabling high brightness emission. The host-guest energy transfer mechanism allows the device to achieve high illumination intensity without requiring complex device structures, as the enhancement comes from the material system rather than structural complexity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the condensed cyclic compound results in an organic light-emitting device with high efficiency, low voltage, high brightness, and extended lifespan by optimizing hole transfer and energy transfer processes.

Implementation Method 1

enhances hole transfer characteristics

Methodology Applied
Scientific EffectHole transfer: Conduction (electrical)

Implementation Method 2

facilitating energy transfer and improving device performance

Methodology Applied
Scientific EffectEnergy transfer: Fluorescence

Implementation Method 3

Carriers, such as holes and electrons, recombine in the emission layer to produce excitons. These excitons transition from an excited state to a ground state, thereby generating light.

Methodology Applied
Scientific EffectLight emission: Electroluminescence

Data Source

PatentUS11552260B2Condensed cyclic compound and organic light-emitting device including the same
Publication Date: 2023.01.10 SAMSUNG DISPLAY CO LTD
  • US11552260B2 patent drawing
  • US11552260B2 patent drawing
  • US11552260B2 patent drawing

AI summary

Provided are a condensed cyclic compound having the following structure:wherein ring D1 and ring D2 are each independently a C6-C20 aromatic ring, and an organic light-emitting device including the same.