Condensed Cyclic Compound for OLED Thermal Stability

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Solution Overview

Problem

Existing organic light-emitting devices face issues with heat resistance and uniformity of the organic layer, leading to unsatisfactory light emission lifespan due to degradation from driving heat and non-uniform film thickness during the solvent removal process in solution coating.

Innovation Solution

Incorporating a condensed cyclic compound with high glass transition temperature and azine-containing groups, which enhances thermal stability, electron transport, and solubility, allowing for improved uniformity and longevity of the organic light-emitting device through solution coating.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of stationary object

If existing compounds are used in the organic layer, then the device can be manufactured, but the compounds degrade due to driving heat resulting in unsatisfactory light emission lifespan

Engineering Contradiction:
Improvelight emission lifespanVSAvoidheat resistance
Core Design Contradiction:
Duration of action of stationary objectVSReliability

Solution Approach 1:

The patent introduces a novel condensed cyclic compound with specific molecular structure parameters (glass transition temperature of 120°C or higher, specific chemical formulas with azine-containing groups) that fundamentally changes the thermal stability parameter of the organic layer, preventing degradation at operating temperatures and extending light emission lifespan

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite organic layer system by combining the condensed cyclic compound (Formula 1 or 2) with other organic materials, where the condensed cyclic compound serves as a thermally stable host or matrix material that protects the overall system from heat-induced degradation

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If solution coating is used to form the organic layer, then manufacturing cost is reduced and material efficiency is improved, but non-uniform film thickness occurs during solvent removal

Engineering Contradiction:
Improvemanufacturing costVSAvoidfilm thickness uniformity
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent modifies the chemical parameters of the organic material by introducing condensed cyclic structures with specific functional groups that enhance solubility in common solvents while maintaining high glass transition temperatures, enabling solution coating to produce uniform films without the non-uniformity problems of conventional materials

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces local structural features (azine-containing groups, specific cyclic structures) within the molecular design that create optimal local interactions between the organic material and solvent, ensuring uniform evaporation and film formation during the solution coating process

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the condensed cyclic compound results in an organic light-emitting device with improved thermal stability and extended light emission lifespan, ensuring efficient film formation and balanced electron-hole transport.

Implementation Method 1

a condensed cyclic compound having a glass transition temperature of 120°C or higher, wherein the condensed cyclic compound has a structure represented by Formula (1) or Formula (2)

Methodology Applied
Scientific EffectThermal energy absorption: Heat Treatment

Implementation Method 2

The light-emitting material is excited by recombination of holes and electrons in the organic layer, and light is generated when the excited light-emitting material transits from an excited state to a ground state

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentEP3184522B1Condensed cyclic compound, composition including the condensed cyclic compound, organic light-emitting device including the condensed cyclic compound, and method of manufacturing the organic light-emitting device
Publication Date: 2023.01.11 SAMSUNG ELECTRONICS CO LTD
  • EP3184522B1 patent drawingFigure 1
  • EP3184522B1 patent drawing
  • EP3184522B1 patent drawing

AI summary

A condensed cyclic compound, a composition including the condensed cyclic compound, an organic light-emitting device including the condensed cyclic compound, and a method of manufacturing the organic light-emitting device are provided.