Condensed Cyclic Compounds for OLEDs with Low Driving Voltage

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Solution Overview

Problem

Current organic light-emitting devices (OLEDs) face challenges in achieving low driving voltage, high efficiency, and long lifespan while maintaining high brightness.

Innovation Solution

The development of novel condensed cyclic compounds represented by Formula 1, which are incorporated into the organic light-emitting device's emission layer, enabling improved electron transport and forming a bipolar structure to enhance electrical characteristics and thermal stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic light-emitting devices are used, then they can provide multicolored images with wide viewing angles, but they suffer from high driving voltage and limited lifespan

Engineering Contradiction:
ImprovelifespanVSAvoiddriving voltage
Core Design Contradiction:
ReliabilityVSUse of energy by stationary object

Solution Approach 1:

The patent modifies the molecular structure parameters of the organic compounds by introducing specific heteroatoms (B, Si, Ge, Sn) and cyclic structures, which changes the electronic properties and energy levels of the materials. This enables lower driving voltage and improved device stability without sacrificing performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite organic compounds that integrate multiple functional units including electron transport groups, hole transport groups, and light-emitting moieties within a single molecular structure. This composite approach allows simultaneous optimization of multiple device characteristics including voltage, efficiency, and lifespan

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional organic light-emitting devices are used, then they can achieve high brightness, but they suffer from low efficiency

Engineering Contradiction:
ImproveefficiencyVSAvoidbrightness
Core Design Contradiction:
ProductivityVSIllumination intensity

Solution Approach 1:

The patent introduces specific functional groups and moieties at particular positions within the molecular structure to optimize local electronic properties. This localized optimization of electron and hole transport regions enhances recombination efficiency while maintaining high brightness output

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses specific organic compounds as intermediary materials between electrodes and emission layers, facilitating efficient charge transport and energy transfer. These intermediary compounds act as mediators that improve overall device efficiency while supporting high brightness operation

Inventive Principle:
Principle #24Intermediary (Mediator)

3Stability of the object's composition

If conventional organic light-emitting devices are used, then they can operate with simple structure, but they lack thermal stability

Engineering Contradiction:
Improvethermal stabilityVSAvoidcompound structure
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent divides the organic compound into distinct functional segments including heteroatom-containing rings, aromatic cores, and substituent groups. This segmentation allows independent optimization of thermal stability through specific structural elements while maintaining overall device functionality

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent incorporates thermally stable heteroatom structures and rigid cyclic frameworks into the organic compounds before device operation. These pre-integrated stable structures provide thermal cushioning that protects the device from degradation during high-temperature operation

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of these compounds results in OLEDs with low driving voltage, high efficiency, high luminance, and extended lifetime due to their improved thermal stability and bipolar structure, facilitating efficient exciton recombination and emission.

Implementation Method 1

Carriers such as the holes and electrons recombine in the emission layer to generate excitons. When the excitons drop from an excited state to a ground state, light is emitted.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9850253B2Condensed cyclic compound and organic light emitting device including the same
Publication Date: 2017.12.26 SAMSUNG ELECTRONICS CO LTD
  • US9850253B2 patent drawing
  • US9850253B2 patent drawing
  • US9850253B2 patent drawing

AI summary

A condensed cyclic compound represented by Formula 1:wherein in Formula 1, A1, A11, X21, XY1, XY11, R4, R14, b4, b14, c1, and c11 are as described in the specification.