Condensed Cyclic Compounds for OLED Electron Transport

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Organic light-emitting devices (OLEDs) face challenges in achieving low driving voltage, high efficiency, and long lifespan while maintaining high brightness.

Innovation Solution

The development of novel condensed cyclic compounds represented by Formulae 1A to 1C, which are incorporated into the organic layer of OLEDs, enhancing the device's performance by acting as an electron transport moiety and improving bipolar characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If conventional organic compounds are used in OLEDs, then the device structure is simpler, but the driving voltage is high and efficiency is low

Engineering Contradiction:
Improvedriving voltageVSAvoidmolecular structure complexity
Core Design Contradiction:
PowerVSDevice complexity

Solution Approach 1:

The patent changes the molecular parameters by introducing condensed cyclic structures with specific heteroatoms (nitrogen, oxygen, sulfur) and adjusting the ring sizes (C3-C10 cycloalkyl, C2-C10 heterocycloalkyl, etc.). These parameter changes in the molecular structure lead to improved electron transport properties and bipolar characteristics, thereby reducing driving voltage and enhancing efficiency without excessive complexity increase

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite molecular structures combining multiple ring systems (cycloalkyl, heterocycloalkyl, aryl, heteroaryl groups) with specific substituents (Formulae 2A-2F). This composite approach creates molecules with optimized electronic properties that balance structural complexity with performance benefits, achieving low driving voltage and high efficiency

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional organic compounds are used in OLEDs, then the manufacturing process is simpler, but the device efficiency and brightness are insufficient

Engineering Contradiction:
Improvedevice efficiencyVSAvoidsynthesis complexity
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent optimizes molecular parameters including ring size (C3-C10), heteroatom types and positions, and substituent groups (Formulae 2A-2F) to enhance electron mobility and recombination efficiency. These parameter optimizations improve device efficiency and brightness while maintaining reasonable synthetic pathways through systematic molecular design

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The complex molecular structures are segmented into modular components: core cyclic structures (Formulae 1A-1C), substituent groups (Formulae 2A-2F), and variable parameters (c1, c2, c11, c12, c13, p1, p2, p11, p12, p13). This segmentation allows for systematic synthesis and optimization, making the manufacturing process more manageable despite the advanced molecular complexity required for high efficiency

Inventive Principle:
Principle #1Segmentation

3Duration of action of stationary object

If conventional organic compounds are used in OLEDs, then the device has shorter response time, but the lifespan is limited

Engineering Contradiction:
Improvedevice lifespanVSAvoidcompound structure complexity
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent introduces specific structural parameters including condensed cyclic frameworks (Formulae 1A-1C) with controlled ring sizes and heteroatom configurations. These parameter changes enhance molecular stability and resistance to degradation, thereby extending device lifespan while managing structural complexity through defined molecular architectures

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent designs compounds with inherent stability features (condensed cyclic structures, stable heteroatom configurations) that resist degradation over time. This approach creates more durable OLED materials that maintain performance longer, effectively extending device lifespan without requiring excessively complex protective structures

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of these compounds results in OLEDs with low driving voltage, high efficiency, and extended lifespan, making them suitable for use in organic light-emitting devices as a host material for emission layers.

Implementation Method 1

enhancing the device's performance by acting as an electron transport moiety

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 2

Carriers, such as holes and electrons, are recombined in the emission layer to produce excitons. These excitons change from an excited state to a ground state, thereby generating light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9771373B2Condensed cyclic compound and organic light-emitting device including the same
Publication Date: 2017.09.26 SAMSUNG ELECTRONICS CO LTD
  • US9771373B2 patent drawing
  • US9771373B2 patent drawing
  • US9771373B2 patent drawing

AI summary

A condensed cyclic compound represented by one of Formulae 1A to 1C, wherein Formulae 1A to 1C are disclosed in the detailed description.