Condensed-Cyclic Compounds for OLED Electron Transport

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Solution Overview

Problem

Current organic light-emitting devices face limitations in achieving high efficiency, low driving voltage, and long lifespan due to the lack of effective condensed-cyclic compounds in their electron transport regions.

Innovation Solution

The development of novel condensed-cyclic compounds represented by Formula 1, which are integrated into the organic light-emitting device's electron transport layer, enhancing intermolecular bonding forces and improving the device's efficiency, brightness, and lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional electron transport materials are used in OLEDs, then device structure is simple and manufacturing is easier, but device efficiency is low, driving voltage is high, and lifespan is short

Engineering Contradiction:
Improvedevice efficiencyVSAvoiddriving voltage
Core Design Contradiction:
ProductivityVSUse of energy by stationary object

Solution Approach 1:

The patent introduces condensed-cyclic compounds with specific molecular structures (Formula 1) that have optimized electronic parameters including electron mobility, LUMO energy levels, and molecular packing characteristics. These parameter changes in the electron transport layer materials enable higher device efficiency while reducing driving voltage through improved charge transport properties

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material strategies by combining condensed-cyclic compounds with other electron transport materials or dopants in the electron transport layer. This creates synergistic effects that enhance electron mobility and reduce energy consumption, achieving both high efficiency and low driving voltage simultaneously

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional electron transport materials are used in OLEDs, then device structure is simple, but device lifespan is short

Engineering Contradiction:
Improvedevice lifespanVSAvoidcompound structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The condensed-cyclic compounds in Formula 1 are designed with specific structural parameters including condensed ring systems and substituent groups that enhance molecular stability, thermal stability, and resistance to degradation. These parameter changes improve device lifespan by preventing material decomposition and maintaining stable electron transport properties over time

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops stable condensed-cyclic compounds that replace conventional short-lifespan electron transport materials. The enhanced molecular stability and resistance to electrochemical degradation allow the electron transport layer to maintain functionality throughout the device's operational lifetime, effectively creating a long-lasting component

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Productivity

If condensed-cyclic compounds with enhanced intermolecular bonding are used, then electron transport performance improves, but synthesis complexity increases

Engineering Contradiction:
Improveelectron transport efficiencyVSAvoidsynthesis ease
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent optimizes the balance between intermolecular bonding strength and synthesis complexity by carefully selecting substituent groups and ring structures in Formula 1. The compounds are designed to achieve sufficient π-π stacking and intermolecular interactions for high electron mobility while using commercially available starting materials and standard organic synthesis techniques, maintaining ease of manufacture

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of these compounds results in an organic light-emitting device with improved efficiency, low driving voltage, high brightness, and extended lifespan by optimizing the electron transport layer's performance.

Implementation Method 1

enhancing intermolecular bonding forces

Methodology Applied
Scientific EffectIntermolecular bonding: Van der Waals Force

Implementation Method 2

electrons provided from the second electrode may move toward the emission layer through the electron transport region

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 3

Carriers, such as holes and electrons, are recombined in the emission layer to produce excitons. These excitons change from an excited state to a ground state, thereby generating light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9837614B2Condensed-cyclic compound and organic light-emitting device comprising the same
Publication Date: 2017.12.05 SAMSUNG DISPLAY CO LTD
  • US9837614B2 patent drawing
  • US9837614B2 patent drawing
  • US9837614B2 patent drawing

AI summary

A condensed-cyclic compound represented by Formula 1 and an organic light-emitting device including the condensed-cyclic compound.wherein R1 to R10 are defined as in the specification.