Condensed Cyclic Compounds for OLED Emission Layer Voltage and Lifespan

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Solution Overview

Problem

Current organic light-emitting devices face limitations in achieving optimal performance in terms of driving voltage, efficiency, luminance, and lifespan due to the lack of materials with suitable triplet energy levels and thermal stability for use in emission layers.

Innovation Solution

The development of novel condensed cyclic compounds represented by Formulae 1B to 1D, which are integrated into the organic light-emitting device's emission layer, offering excellent heat resistance and a suitable triplet energy level, enabling low driving voltage, high efficiency, and long lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If conventional materials are used in the emission layer, then the device structure is simple, but the driving voltage is high and efficiency is low

Engineering Contradiction:
Improvedriving voltageVSAvoidmaterial structure
Core Design Contradiction:
PowerVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by modifying the chemical structure of organic compounds in the emission layer, specifically incorporating condensed cyclic structures with appropriate triplet energy levels. This structural modification changes the energy parameters of the material, enabling lower driving voltage operation while maintaining device simplicity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by combining specific host materials with condensed cyclic emitter compounds having complementary properties. The host material provides structural framework while the condensed cyclic compound contributes appropriate triplet energy levels, creating a synergistic emission layer that achieves low driving voltage without complex device architecture

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional materials are used in the emission layer, then the manufacturing process is simple, but the luminance and efficiency are insufficient

Engineering Contradiction:
ImproveluminanceVSAvoidmaterial selection
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent changes the energy level parameters of emission layer materials by introducing condensed cyclic compounds with optimized triplet energy levels. This parameter optimization enables high luminance output while maintaining straightforward manufacturing processes, as the compounds can be deposited using conventional vacuum deposition techniques without requiring complex multi-layer structures

Inventive Principle:
Principle #35Parameter changes

3Duration of action of stationary object

If materials with unsuitable triplet energy levels are used, then the device is simple to manufacture, but the lifespan is short

Engineering Contradiction:
ImprovelifespanVSAvoidmaterial properties
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent addresses lifespan by changing the triplet energy level parameter of the emission layer materials to match or exceed that of the host material. This parameter matching prevents energy back-transfer that degrades the host material, thereby extending device lifespan while maintaining simple material composition without requiring complex protective layers or structures

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of these condensed cyclic compounds results in organic light-emitting devices with lower driving voltage, higher efficiency, higher luminance, and extended lifespan, while also serving as suitable hosts or emitters in the emission layer.

Implementation Method 1

Carriers, such as holes and electrons, are recombined in the emission layer to produce excitons. These excitons change from an excited state to a ground state, thereby generating light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentEP2966146B1Condensed cyclic compound and organic light-emitting device including the same
Publication Date: 2019.09.11 SAMSUNG ELECTRONICS CO LTD
  • EP2966146B1 patent drawingFigure 1
  • EP2966146B1 patent drawingFigure 2
  • EP2966146B1 patent drawingFigure 3

AI summary

Provided are a condensed cyclic compound and an organic light-emitting device including the condensed cyclic compound.