Condensed-Cyclic Compound for OLED Emission Layer Efficiency

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Solution Overview

Problem

Current organic light-emitting diodes (OLEDs) face limitations in achieving optimal performance due to the need for improved materials that enhance light emission efficiency and stability, particularly in the emission layer, which affects the overall brightness and lifespan of the devices.

Innovation Solution

A condensed-cyclic compound represented by Formula 1 is introduced, which can be used in the emission layer of OLEDs, comprising specific aryl and heterocyclic groups, allowing for enhanced light emission and improved device performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic compounds are used in the emission layer, then the device structure can be maintained, but light emission efficiency and device lifespan are insufficient

Engineering Contradiction:
Improvedevice lifespanVSAvoidlight emission efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent modifies the molecular structure parameters of organic compounds by introducing condensed-cyclic structures with specific aryl and heterocyclic groups (Formula 1), changing the chemical composition parameters to achieve both improved stability for longer lifespan and enhanced light emission efficiency simultaneously

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite organic compounds combining multiple functional groups (aryl groups, heterocyclic groups, and condensed-cyclic structures) in a single molecular framework (Formula 1), creating materials that exhibit both high stability and high light emission efficiency that neither component achieves alone

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If the emission layer materials are improved for higher efficiency, then brightness and efficiency increase, but material complexity increases

Engineering Contradiction:
ImprovebrightnessVSAvoidmaterial complexity
Core Design Contradiction:
Illumination intensityVSDevice complexity

Solution Approach 1:

The complex molecular structure (Formula 1) is segmented into distinct functional modules: condensed-cyclic core structure, aryl groups (A1), heterocyclic groups, and substituent groups (R1-R13), allowing systematic design and optimization of brightness while managing complexity through modular construction

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the molecular structure serve specific local functions: the condensed-cyclic core provides structural stability, aryl groups contribute to rigidity and electron delocalization for brightness, while heterocyclic groups and substituents fine-tune electronic properties, achieving high brightness without uniform complexity throughout the entire material system

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the condensed-cyclic compound in the OLED emission layer results in higher efficiency and longer lifespan, as demonstrated by the improved driving voltage, current density, brightness, and efficiency of the OLEDs, making them suitable for flat panel display devices.

Implementation Method 1

When a voltage is applied between the anode and the cathode, holes injected from the anode move to the EML via the HTL, and electrons injected from the cathode move to the EML via the ETL. The holes and electrons recombine in the EML to generate excitons. When the excitons drop from an excited state to a ground state, light is emitted.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9224961B2Condensed-cyclic compound, organic light-emitting diode comprising the same and flat panel display device comprising the organic light-emitting diode
Publication Date: 2015.12.29 SAMSUNG DISPLAY CO LTD
  • US9224961B2 patent drawing
  • US9224961B2 patent drawing
  • US9224961B2 patent drawing

AI summary

A condensed-cyclic compound of Formula 1, an organic light-emitting diode (OLED) including the same and a flat panel display device including the OLED. The condensed-cyclic compound of Formula 1 may be used in an organic light-emitting diode. Accordingly, an OLED according to an embodiment of the present invention includes a first electrode, a second electrode disposed opposite to the first electrode, and a first layer interposed between the first electrode and the second electrode, wherein the first layer includes the condensed-cyclic compound represented by Formula 1. The OLED may further include at least one layer selected from the group consisting of a hole injection layer, a hole transport layer, an emission layer, a hole blocking layer, an electron transport layer and an electron injection layer.