Condensed Cyclic Compound for OLED Emission Layer Stability

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Solution Overview

Problem

Current organic light-emitting devices (OLEDs) face limitations in achieving optimal performance due to challenges in the design of emission layers and electron transport regions, which affect the efficiency and stability of light emission.

Innovation Solution

A condensed cyclic compound represented by Formula 1 is introduced, which can be used in the organic layer of OLEDs, specifically in the emission layer and electron transport region, to enhance the recombination of holes and electrons, thereby improving light emission efficiency and stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional emission layers and electron transport regions are used in OLEDs, then the device structure is simpler and easier to manufacture, but the light emission efficiency and stability are insufficient

Engineering Contradiction:
Improvelight emission stabilityVSAvoidcompound structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent modifies the molecular structure parameters of the emission layer and electron transport region by introducing specific condensed cyclic compounds with defined ring structures (A1 and A2 rings) and substituent groups (L1-L4). These parameter changes in molecular architecture improve charge transport and recombination efficiency, thereby enhancing light emission stability without requiring fundamental changes to the OLED device structure.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material design by combining heterocyclic groups (A1 ring containing N atom) with cyclic groups (A2 ring) to form condensed cyclic compounds. This composite molecular structure integrates the benefits of both heterocyclic compounds (good charge transport) and cyclic compounds (structural stability), achieving improved emission stability through material composition rather than device structural complexity.

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional emission layers are used in OLEDs, then the manufacturing process is simpler, but the recombination efficiency of holes and electrons is insufficient

Engineering Contradiction:
Improvelight emission efficiencyVSAvoidcompound molecular complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent applies local quality modification by introducing specific functional groups (L1-L4 linkers) and substituent patterns at particular positions within the condensed cyclic compound structure. The A1 ring provides hole transport capability while the A2 ring contributes to electron transport, and the L1-L4 linkers facilitate charge recombination. This localized functional differentiation within the molecule improves recombination efficiency without requiring complex multi-component systems.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent optimizes molecular parameters including ring size (C2-C20 heterocyclic, C6-C20 cyclic), number of linkers (a1-a4 from 0-3), and substituent types (R1-R6) to enhance charge carrier mobility and recombination probability. By adjusting these molecular parameters, the compound achieves higher productivity in light emission while maintaining a manageable structural complexity through systematic molecular design rather than random complexity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the condensed cyclic compound in OLEDs leads to improved light emission efficiency and stability, enabling better performance and potentially wider application in display technologies.

Implementation Method 1

Carriers such as the holes and electrons recombine in the emission layer to generate excitons. When the excitons drop from an excited state to a ground state, light is emitted.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS10087145B2Condensed cyclic compound and organic light-emitting device comprising the same
Publication Date: 2018.10.02 SAMSUNG DISPLAY CO LTD
  • US10087145B2 patent drawing
  • US10087145B2 patent drawing
  • US10087145B2 patent drawing

AI summary

A condensed cyclic compound represented by Formula 1 and an organic light-emitting device including the condensed cyclic compound are provided;