Condensed Cyclic OLED Host Compound for Triplet Energy Control

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Solution Overview

Problem

Current organic light-emitting devices (OLEDs) face limitations in achieving high efficiency and long lifespan due to electron deterioration and triplet-triplet annihilation effects, which affect their performance and durability.

Innovation Solution

A novel condensed cyclic compound represented by Formula 1 is introduced, which includes specific ring structures and substituents, used in the emission layer of OLEDs to enhance host-dopant energy transfer and increase triplet energy levels, thereby reducing electron deterioration and improving efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional organic light-emitting devices are used, then device structure is simple, but efficiency is low and lifespan is short due to electron deterioration and triplet-triplet annihilation

Engineering Contradiction:
Improvedevice efficiencyVSAvoiddevice lifespan
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent modifies the molecular structure parameters of the host material by introducing a condensed cyclic core structure with specific ring configurations (Formula 1). This structural parameter change increases the triplet energy level (ET) of the host material, which fundamentally alters the energy transfer dynamics in the emission layer, thereby simultaneously improving efficiency and lifespan by suppressing triplet-triplet annihilation and electron deterioration

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite emission layer system combining the novel condensed cyclic host compound (Formula 1) with dopant materials. This composite material approach enables optimized host-dopant energy transfer, where the specific host structure promotes efficient energy transfer while the composite nature allows tuning of energy levels to prevent harmful interactions, achieving both high efficiency and long operational lifetime

Inventive Principle:
Principle #40Composite materials

2Productivity

If host-dopant energy transfer is enhanced, then efficiency increases, but device complexity increases due to specific structural requirements

Engineering Contradiction:
Improveenergy transfer efficiencyVSAvoidmolecular structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The host molecule is segmented into distinct functional regions: a condensed cyclic core structure (Formula 1) providing high triplet energy, and substituent groups (L1, L2, R1-R6) that can be independently optimized. This segmentation allows the core structure to handle energy transfer efficiency while substituents can be tailored for specific device requirements, managing complexity through modular design

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent applies local quality by having different parts of the molecule serve different functions: the condensed cyclic core (A1-A6 rings) provides the high triplet energy level for efficient energy transfer, while the substituent positions (R1-R6) and linkers (L1, L2) can be locally optimized for solubility, processing, or specific energy level matching. This localized functional differentiation achieves high energy transfer efficiency without requiring overall molecular complexity

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the condensed cyclic compound in OLEDs leads to increased efficiency and a longer lifespan by promoting appropriate host-dopant energy level adjustments and enhancing triplet exciton annihilation, resulting in improved performance and durability.

Implementation Method 1

enhance host-dopant energy transfer

Methodology Applied
Scientific EffectEnergy transfer:

Implementation Method 2

enhancing triplet exciton annihilation

Methodology Applied
Scientific EffectTriplet exciton annihilation:

Data Source

PatentUS11937502B2Condensed cyclic compound and organic light-emitting device comprising the same
Publication Date: 2024.03.19 SAMSUNG DISPLAY CO LTD
  • US11937502B2 patent drawing
  • US11937502B2 patent drawing
  • US11937502B2 patent drawing

AI summary

A condensed cyclic compound and an organic light-emitting device including the condensed cyclic compound are provided. The condensed cyclic compound is represented by Formula 1. The A3 ring of Formula 1 is a group represented by Formula 2A or a group represented by Formula 2B. The organic light-emitting device includes: a first electrode; a second electrode; and an organic layer between the first electrode and the second electrode and including an emission layer, the organic layer including at least one of the condensed cyclic compound represented by Formula 1.