Condensed Cyclic Compound for OLED Host Material

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Solution Overview

Problem

Current organic light-emitting devices (OLEDs) face challenges in achieving low driving voltage, high efficiency, and long lifespan while maintaining high brightness.

Innovation Solution

A novel condensed cyclic compound represented by Formulae 1A or 1B is integrated into the organic light-emitting device, specifically in the emission layer, which acts as a host and can be used as a red, green, or blue host, adjusting HOMO and LUMO energy levels to optimize the S1 and T1 energy levels for improved performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If conventional organic light-emitting devices are used, then basic light emission is achieved, but driving voltage is high and efficiency is low

Engineering Contradiction:
Improvedriving voltageVSAvoiddevice performance
Core Design Contradiction:
PowerVSReliability

Solution Approach 1:

The patent modifies the energy level parameters of the host material by designing condensed cyclic compounds with specific HOMO and LUMO energy levels. The compound structures are optimized to achieve S1 energy levels of 2.3-3.2 eV and T1 energy levels of 2.5-3.5 eV, which directly controls the driving voltage and efficiency of the OLED device

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material design by combining condensed cyclic compound cores with various aromatic ring systems (Formula 1C) and substituent groups (Formulae 1A and 1B). This composite structure allows tuning of energy levels while maintaining stable device performance, resolving the contradiction between low driving voltage and high reliability

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If brightness is increased, then illumination intensity improves, but device lifespan decreases

Engineering Contradiction:
ImprovebrightnessVSAvoidlifespan
Core Design Contradiction:
Illumination intensityVSDuration of action of stationary object

Solution Approach 1:

The patent optimizes the energy level parameters of the host material to achieve balanced charge carrier recombination. By controlling S1 energy levels (2.3-3.2 eV) and T1 energy levels (2.5-3.5 eV), the device achieves high brightness through efficient exciton formation while maintaining long lifespan through reduced degradation at high operating currents

Inventive Principle:
Principle #35Parameter changes

3Adaptability or versatility

If emission color is adjusted, then versatility improves, but energy level optimization becomes more complex

Engineering Contradiction:
Improveemission color adjustmentVSAvoidenergy level optimization
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent creates a universal host material platform (condensed cyclic compound with Formula 1C core) that can be adapted for multiple emission colors (red, green, blue) by modifying substituent groups (Formulae 1A and 1B). This multi-functional design allows the same core structure to achieve different S1 energy levels (2.3-3.2 eV) for different colors while maintaining consistent device performance characteristics

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent applies local quality modification by changing specific substituent groups (R1-R3, R11-R14, R21-R23) and their positions (a1-a3, a11-a14, a21, b1-b3, b21) on the core structure to tune emission color. This localized modification approach simplifies the optimization process compared to changing the entire molecular structure, as each substituent can be independently optimized for desired energy levels

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the condensed cyclic compound in the OLEDs results in devices with low driving voltage, high efficiency, and extended lifespan, suitable for various emission colors due to adjustable energy levels, enhancing overall device performance.

Implementation Method 1

Carriers, such as holes and electrons, are recombined in the emission layer to produce excitons. These excitons change from an excited state to a ground state, thereby generating light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS10040794B2Condensed cyclic compound and organic light-emitting device including the same
Publication Date: 2018.08.07 SAMSUNG ELECTRONICS CO LTD
  • US10040794B2 patent drawing

AI summary

A condensed cyclic compound represented by Formulae 1A or 1B:wherein in Formulae 1A and 1 B, groups, rings, substituents, and variables are defined in the detailed description.