Condensed Cyclic Compound for OLED Host Material

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Solution Overview

Problem

Current organic light-emitting devices (OLEDs) face challenges in achieving low driving voltage, high efficiency, and long lifespan while maintaining high brightness and balanced carrier injection.

Innovation Solution

Incorporation of a novel condensed cyclic compound, represented by Formula 1C or 1D, as a host in the emission layer of OLEDs, which includes a nitrogen-containing electron transporting moiety fused with a carbazole-based ring, enhancing bipolar characteristics and controlling HOMO and LUMO energy levels.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If conventional organic light-emitting devices are used, then high brightness can be achieved, but driving voltage remains high and lifespan is limited

Engineering Contradiction:
ImprovebrightnessVSAvoidlifespan
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent applies parameter changes by modifying the molecular structure of the host material to achieve optimal HOMO and LUMO energy levels. The condensed cyclic compound with nitrogen-containing electron transporting moiety fused to carbazole-based ring creates specific energy level parameters that enable balanced carrier injection and reduce operating voltage, thereby extending device lifespan while maintaining brightness

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining the nitrogen-containing electron transporting moiety with the carbazole-based ring system to form a novel condensed cyclic compound. This composite molecular structure integrates electron transport capabilities with hole transport capabilities, creating a bipolar host material that improves both efficiency and device reliability

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If conventional organic light-emitting devices are used, then high brightness can be achieved, but driving voltage remains high

Engineering Contradiction:
ImprovebrightnessVSAvoiddriving voltage
Core Design Contradiction:
Illumination intensityVSUse of energy by moving object

Solution Approach 1:

The patent changes the energy level parameters of the host material by designing the condensed cyclic compound with specific HOMO and LUMO levels. This parameter optimization enables lower driving voltage operation while maintaining high brightness output, as the energy levels are tuned to facilitate efficient carrier injection and recombination

Inventive Principle:
Principle #35Parameter changes

3Productivity

If conventional organic light-emitting devices are used, then operation can be maintained, but efficiency and lifespan are insufficient

Engineering Contradiction:
ImproveefficiencyVSAvoidlifespan
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent optimizes the energy level parameters of the host material to achieve balanced carrier injection and recombination efficiency. By tuning the HOMO and LUMO levels of the condensed cyclic compound, the device achieves higher internal quantum efficiency and reduced non-radiative recombination, which simultaneously improves productivity and extends operational lifespan

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The composite molecular structure combining nitrogen-containing electron transporting moiety with carbazole-based ring creates a bipolar host material that enhances both electron and hole transport. This composite structure improves charge balance and recombination efficiency, leading to higher device efficiency and extended lifespan through reduced operational stress

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the condensed cyclic compound improves the efficiency and extends the lifetime of OLEDs by optimizing energy levels and carrier balance, leading to reduced driving voltage and enhanced emission efficiency.

Implementation Method 1

a nitrogen-containing electron transporting moiety fused with a carbazole-based ring, enhancing bipolar characteristics and controlling HOMO and LUMO energy levels

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 2

Carriers such as the holes and electrons recombine in the emission layer to generate excitons. When the excitons drop from an excited state to a ground state, light is emitted

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentEP2894157B1Condensed cyclic compound and organic light-emitting device including the same
Publication Date: 2018.04.04 SAMSUNG ELECTRONICS CO LTD
  • EP2894157B1 patent drawingFigure 1
  • EP2894157B1 patent drawing
  • EP2894157B1 patent drawing

AI summary

A condensed cyclic compound represented by Formula 1, wherein, in Formula 1, L1, E1, R1, X11 to X13, X21 to X26, a1, b1 and c1 are described in the specification. An organic light-emiiting device including such a compound is also disclosed.