Condensed-Cyclic OLED Host Materials for Low-Voltage Emission

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Solution Overview

Problem

Existing organic light-emitting devices (OLEDs) face challenges in achieving low driving voltage, high efficiency, high brightness, and long lifespan.

Innovation Solution

Incorporation of novel condensed-cyclic compounds, represented by specific chemical structures, into the emission layer of OLEDs, which act as hosts for dopants to enhance performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If conventional organic light-emitting devices are used, then basic light emission is achieved, but driving voltage is high and efficiency is low

Engineering Contradiction:
Improvedriving voltageVSAvoiddevice performance
Core Design Contradiction:
PowerVSReliability

Solution Approach 1:

The patent applies parameter changes by modifying the molecular structure of organic compounds in the emission layer, specifically using condensed-cyclic compounds with particular heteroatom arrangements (X1-X4 representing N, O, S atoms in specific configurations). This structural parameter change enables simultaneous achievement of low driving voltage and high efficiency by altering the electronic properties and energy levels of the host materials.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by combining condensed-cyclic host compounds with dopant materials in the emission layer. The specific composite system involves hosts containing fused ring structures with heteroatoms (Formula 1A-1 to 1A-7 and 1B-1 to 1B-4) paired with appropriate dopants, creating a material composition that optimizes both electrical properties for low voltage and optical properties for high efficiency.

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If conventional OLED structures are used, then light emission is achieved, but brightness and lifespan are insufficient

Engineering Contradiction:
ImprovebrightnessVSAvoidlifespan
Core Design Contradiction:
Illumination intensityVSDuration of action of stationary object

Solution Approach 1:

The patent utilizes parameter changes in the molecular architecture of the emission layer compounds, specifically employing condensed-cyclic structures with controlled heteroatom types and positions (X1-X4 selections from N, O, S). These parameter modifications enhance both brightness through improved radiative recombination and lifespan through increased material stability and reduced degradation pathways.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent addresses the brightness-lifespan contradiction by designing organic compounds with optimized stability characteristics, allowing the emission layer materials to maintain high performance over extended operational periods. The condensed-cyclic structures provide enhanced molecular stability that prevents rapid degradation, effectively extending device lifespan while maintaining high brightness output.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of these compounds improves the efficiency and longevity of OLEDs while maintaining low driving voltage.

Implementation Method 1

Carriers such as holes and electrons recombine in the EML to generate excitons. When the excitons drop from an excited state to a ground state, light is emitted.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS12384766B2Condensed cyclic compound and organic light-emitting device including the same
Publication Date: 2025.08.12 SAMSUNG ELECTRONICS CO LTD
  • US12384766B2 patent drawing
  • US12384766B2 patent drawing
  • US12384766B2 patent drawing

AI summary

A condensed-cyclic compound represented by Formula 1A:wherein in Formula 1A, groups, substituents, and variables are the same as defined in the specification.