Condensed Cyclic Compound Host for OLED Efficiency and Lifespan

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Organic light-emitting devices (OLEDs) face challenges in achieving low driving voltage, high efficiency, high brightness, and long lifespan while maintaining high quantum luminance efficiency.

Innovation Solution

Incorporation of a novel condensed cyclic compound represented by Formula 1 into the organic layer of OLEDs, which includes an emission layer, hole transport region, and electron transport region, serving as a host for phosphorescent dopants to enhance device performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If conventional organic compounds are used in OLEDs, then device structure is simple, but driving voltage is high and efficiency is low

Engineering Contradiction:
Improvedriving voltageVSAvoidcompound structure complexity
Core Design Contradiction:
PowerVSDevice complexity

Solution Approach 1:

The patent changes the chemical parameters of the host compound by introducing condensed cyclic structures with specific heteroatoms (X1, X2, X3) and substituents (R1-R9, R11-R18), which fundamentally alters the electronic properties, HOMO-LUMO energy levels, and molecular packing of the material, thereby reducing driving voltage and improving efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite molecular structures by combining condensed cyclic cores with various functional groups and substituents, forming hybrid compounds that integrate multiple properties (electron transport, hole transport, stability, luminescence) into a single host material system

Inventive Principle:
Principle #40Composite materials

2Use of energy by moving object

If conventional organic compounds are used in OLEDs, then manufacturing is easy, but luminance efficiency is low

Engineering Contradiction:
Improveluminance efficiencyVSAvoidcompound synthesis difficulty
Core Design Contradiction:
Use of energy by moving objectVSEase of manufacture

Solution Approach 1:

The patent applies local quality by designing specific regions of the molecule with distinct functions: the condensed cyclic core provides structural stability and electron delocalization, while specific substituents (R1-R9) at different positions optimize electron transport, hole transport, and luminescence properties locally, achieving high overall luminance efficiency

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent optimizes luminance efficiency by precisely controlling molecular parameters including HOMO-LUMO energy gap, electron affinity, ionization potential, and molecular weight through systematic variation of substituents and core structures, enabling fine-tuning of device performance

Inventive Principle:
Principle #35Parameter changes

3Duration of action of stationary object

If conventional organic compounds are used in OLEDs, then device lifespan is limited, but compound complexity is low

Engineering Contradiction:
Improvedevice lifespanVSAvoidmolecular structure complexity
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent extends device lifespan by changing the chemical stability parameters of the host compound through condensed cyclic structures that resist oxidation, degradation, and morphological changes under operational stress, maintaining structural integrity over extended periods

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent incorporates protective structural features in advance, such as sterically hindered substituents and robust condensed cyclic frameworks, that prevent degradation pathways before they can occur during device operation, cushioning against chemical and physical degradation

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the condensed cyclic compound results in OLEDs with low driving voltage, high efficiency, high luminance, and extended lifespan, suitable for green or blue emission layers.

Implementation Method 1

Holes provided from the anode may move toward the emission layer through the hole transport region, and electrons provided from the cathode may move toward the emission layer through the electron transport region. The holes and the electrons are recombined in the emission layer to produce excitons, which then change from an excited state to a ground state, generating light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS10581000B2Condensed cyclic compound and organic light-emitting device including the same
Publication Date: 2020.03.03 SAMSUNG ELECTRONICS CO LTD
  • US10581000B2 patent drawing
  • US10581000B2 patent drawing
  • US10581000B2 patent drawing

AI summary

A condensed cyclic compound represented by Formula 1:wherein in Formula 1, groups X1 to X3 and X11 to X18 are the same as described in the specification.