Condensed Cyclic TADF Emitter for Low-Voltage OLED Luminance

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Solution Overview

Problem

Existing organic light-emitting devices face challenges in achieving enhanced performance in terms of luminance, driving voltage, and response speed, particularly in producing full-color images with wide viewing angles and short response times.

Innovation Solution

Incorporating a condensed cyclic compound represented by Formula 1 into the emission layer of the light-emitting device, which can serve as a thermally activated delayed fluorescence (TADF) emitter, enhancing the device's performance by improving luminance and response speed.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If conventional organic light-emitting devices are used, then basic light emission is achieved, but luminance and response speed are insufficient

Engineering Contradiction:
ImproveluminanceVSAvoidresponse speed
Core Design Contradiction:
Illumination intensityVSSpeed

Solution Approach 1:

The patent applies parameter changes by modifying the molecular structure of the emission layer through condensed cyclic compounds with specific formulas (Formula 1, 1A, 2, 3). These structural parameters include ring systems (CY1-CY4), substituents (R1-R8), and connection groups (L1-L4, Y1-Y4), which are optimized to achieve both high luminance and fast response speed simultaneously

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite materials by combining the condensed cyclic compound (Formula 1) with host materials in the emission layer. The compound serves as a dopant with specific concentration ranges (0.1-10 wt%), creating a composite emission system that leverages the synergistic effects of both components to improve luminance and response characteristics

Inventive Principle:
Principle #40Composite materials

2Use of energy by moving object

If driving voltage is reduced, then energy efficiency improves, but luminance performance may deteriorate

Engineering Contradiction:
Improvedriving voltageVSAvoidluminance
Core Design Contradiction:
Use of energy by moving objectVSIllumination intensity

Solution Approach 1:

The patent changes the electrical parameters of the device by using condensed cyclic compounds with optimized HOMO-LUMO energy levels. The molecular structure parameters (Formula 1, 1A, 2, 3) are designed to achieve favorable charge injection and transport properties, enabling low driving voltage operation while maintaining high luminance output

Inventive Principle:
Principle #35Parameter changes

3Adaptability or versatility

If full-color image production is achieved, then device functionality is enhanced, but response time increases

Engineering Contradiction:
Improvefull-color image productionVSAvoidresponse time
Core Design Contradiction:
Adaptability or versatilityVSLoss of time

Solution Approach 1:

The patent applies local quality by using different condensed cyclic compounds (Formula 1, 2, or 3) in different emission layers or sub-pixels to produce different colors (red, green, blue). Each local region is optimized with specific molecular structures that maintain fast response characteristics while achieving full-color display capability

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention utilizes periodic action through the use of thermally activated delayed fluorescence (TADF) mechanisms with specific lifetime characteristics. The emission process involves periodic transitions between singlet and triplet states, enabling efficient color production with controlled response times through molecular design

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the condensed cyclic compound results in improved luminance and response speed, enabling the production of full-color images with wide viewing angles and reduced driving voltage.

Implementation Method 1

the condensed cyclic compound may serve as a thermally activated delayed fluorescence (TADF) emitter, and the emission layer may emit delayed fluorescence

Methodology Applied
Scientific EffectThermally activated delayed fluorescence (TADF): Fluorescence

Data Source

PatentUS20250359482A1Light-emitting device including condensed cyclic compound, electronic apparatus including the light-emitting device, and the condensed cyclic compound
Publication Date: 2025.11.20 SAMSUNG DISPLAY CO LTD
  • US20250359482A1 patent drawing
  • US20250359482A1 patent drawing
  • US20250359482A1 patent drawing

AI summary

Embodiments provide a condensed cyclic compound, a light-emitting device including the condensed cyclic compound, and an electronic apparatus including the light-emitting device. The light-emitting device includes a first electrode, a second electrode facing the first electrode, and an interlayer between the first electrode and the second electrode, wherein the interlayer includes an emission layer, and the condensed cyclic compound. The condensed cyclic compound is represented by Formula 1, which is explained in the specification: