Conductive Adhesive Electrode Patch for Stable Long-Term Skin Contact

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Solution Overview

Problem

Existing skin surface electrodes face challenges with long-term stability, skin irritation, and moisture-induced resistance changes, particularly in gel-based and polymer-based systems, which affect their reliability and homogeneity in electrophysical measurements.

Innovation Solution

A layered body comprising a substrate with a conductive adhesive layer made from a polymer matrix and cationic polythiophene/polymeric anion particles, which is self-adhesive and maintains low resistance without the need for liquid electrolytes, ensuring immediate and long-term reliable measurements.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If gel-based electrodes are used for skin contact, then good initial adhesion is achieved, but long-term stability deteriorates due to moisture-induced resistance changes and skin irritation

Engineering Contradiction:
Improvelong-term stabilityVSAvoidskin irritation
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The invention changes the chemical composition parameters by replacing traditional gel electrolytes with a specific polymer composition (polymer A with carboxylic acid groups and polymer B as conductive polymer) that maintains adhesion without causing skin irritation. The polymer ratio and molecular weight parameters are optimized to achieve both adhesion and long-term stability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite material system combining two different polymers (polymer A with carboxylic acid groups for adhesion and polymer B conductive polymer for electrical conductivity) to achieve properties that neither material alone could provide, resolving the contradiction between adhesion and long-term stability.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If conductive polymer systems are used for long-term applications, then skin compatibility is improved, but transition resistance changes due to moisture absorption

Engineering Contradiction:
Improveskin compatibilityVSAvoidtransition resistance stability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The invention modifies the polymer composition parameters by selecting polymers with specific glass transition temperatures and functional groups that reduce moisture absorption. The carboxylic acid groups in polymer A form hydrogen bonds that stabilize the structure against moisture-induced changes.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The carboxylic acid groups in polymer A act as intermediaries that form hydrogen bonding networks, mediating between the conductive polymer B and the external environment to prevent moisture from directly affecting the conductive properties.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If metallic conductive structures are used to achieve homogeneous potential distribution, then measurement homogeneity is improved, but fabrication complexity and cost increase

Engineering Contradiction:
Improvepotential distribution homogeneityVSAvoidfabrication complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention replaces complex metallic conductive structures with a uniformly applied polymer-based conductive adhesive layer. The conductive polymer B distributed throughout the adhesive matrix provides homogeneous conductivity without requiring precision metal patterning or complex fabrication processes.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention achieves homogeneous potential distribution through a homogeneous distribution of conductive polymer B particles throughout the adhesive layer, eliminating the need for complex metallic trace patterns. The uniform composition ensures consistent electrical properties across the entire electrode surface.

Inventive Principle:
Principle #33Homogeneity

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a self-adhesive, cost-effective, and reliable skin surface electrode with stable electrical properties, resistant to moisture-induced changes, suitable for long-term applications in electrophysical measurements.

Implementation Method 1

the conductive adhesive layer comprises IIa) a polymer forming a matrix and IIb) particles of a conductive polymer distributed in the matrix

Methodology Applied
Scientific EffectElectrical Conductivity: Conduction (electrical)

Implementation Method 2

the polymer comprises repeating units having the general structure —CH2—CR1—COOR2— wherein R1 represent H or an alkyl group and R2 represents an optionally substituted C1-C10-alkyl group

Methodology Applied
Scientific EffectHydrogen bonding: Chemical Bonding

Data Source

PatentUS11980478B2Self-adhesive electrode patch
Publication Date: 2024.05.14 HERAEUS EPURIO GMBH
  • US11980478B2 patent drawing
  • US11980478B2 patent drawing
  • US11980478B2 patent drawing

AI summary

Disclosed is a layered body comprising a polymer comprising repeating units having the general structure —CH2—CHR1—COOR2— as defined herein, to a process for producing such a layered body, to a layered body produced by that process and to the use of a layered body for electrophysical measurements.