Conductive Composition for Wafer Coating

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Solution Overview

Problem

Current conductive adhesive solutions for semiconductor wafer bonding face challenges such as high cost, bond line stress, limited throughput, and inadequate conductivity, particularly when replacing eutectic bonding methods, which require high thermal expansion materials and gold plating, and struggle with small die sizes and fragile substrates.

Innovation Solution

A conductive composition for semiconductor wafers comprising 66-80 wt% conductive filler with an average particle size under 2 microns, 5-25 wt% first resin with a softening point between 80-260°C, 5-25 wt% solvent, and 0-5 wt% curing agent, allowing for high electrical and thermal conductivity, smooth surface, and fast curing, which can be printed and B-staged for uniform coverage and high strength.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If eutectic bonding with gold-silicon alloy is used, then high bond strength and fast processing are achieved, but cost increases due to gold plating and lead line stress increases due to high modulus and high processing temperatures

Engineering Contradiction:
Improveprocessing speedVSAvoidbond line stress
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the bonding material from traditional eutectic alloys to organic-inorganic hybrid compositions with specific functional groups (isocyanate, hydroxyl, carboxyl). This parameter change allows bonding at lower temperatures (reducing thermal stress) while maintaining fast processing speeds through optimized rheological properties of the hybrid composition.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials combining organic resin components with inorganic filler particles. This composite structure provides both the adhesion benefits of organic materials and the mechanical strength of inorganic materials, reducing bond line stress while maintaining high bond strength and fast processing capability without requiring gold plating.

Inventive Principle:
Principle #40Composite materials

2Strength

If conventional eutectic bonding is used, then high bond strength is achieved, but cost increases and stress causes die cracking especially with fragile substrates like gallium arsenide

Engineering Contradiction:
Improvebond strengthVSAvoiddie stress and cracking
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent modifies the bonding material composition to include organic-inorganic hybrids with specific functional groups that provide strong adhesion at lower curing temperatures. This parameter change reduces thermal stress on fragile dies while maintaining high bond strength, preventing die cracking in sensitive substrates like gallium arsenide RF power amplifier devices.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces expensive gold-based eutectic materials with cost-effective organic-inorganic hybrid compositions. These hybrid materials provide comparable or superior bonding performance without the high cost of gold plating and without the high modulus that causes die stress, making them ideal for fragile semiconductor devices.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Object-affected harmful factors

If dispensed conductive paste adhesive is used, then cost is reduced and stress is lowered, but throughput decreases due to dispensing time and electrical conductivity is insufficient

Engineering Contradiction:
Improvebond line stressVSAvoidproduction rate
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent uses composite organic-inorganic hybrid materials that combine the low-stress advantages of organic adhesives with the high conductivity and fast-curing properties of inorganic materials. This composite approach enables screen printing processing (high throughput) while maintaining low bond line stress and achieving high electrical conductivity through the inorganic conductive filler content.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the material composition to include conductive inorganic fillers within the organic-inorganic hybrid matrix, optimizing the balance between viscosity (for screen printing), conductivity (through filler content), and curing speed. This parameter optimization enables high-throughput screen printing while maintaining low stress and high electrical conductivity.

Inventive Principle:
Principle #35Parameter changes

4Object-affected harmful factors

If lead-free solder materials are used, then environmental hazard is reduced, but bond line stress increases and conductivity is insufficient

Engineering Contradiction:
Improveenvironmental hazardVSAvoidbond line stress
Core Design Contradiction:
Object-affected harmful factorsVSStress or pressure

Solution Approach 1:

The patent employs organic-inorganic composite hybrid materials that replace lead-free solder alloys. These composites combine organic resin matrices with inorganic conductive fillers, providing low bond line stress (unlike rigid solder materials) while maintaining high electrical conductivity through the conductive filler network. This approach is environmentally friendly and suitable for fragile semiconductor devices.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a high-conductivity, low-stress adhesive with improved throughput and reduced costs, suitable for small die sizes, and compatible with existing manufacturing infrastructure, addressing the limitations of traditional adhesives by ensuring reliable bonding and minimizing die tilt and delamination issues.

Implementation Method 1

high electrical and thermal conductivity

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 2

high electrical and thermal conductivity

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Implementation Method 3

evaporating the solvent from the conductive composition

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS7422707B2Highly conductive composition for wafer coating
Publication Date: 2008.09.09 HENKEL KGAA
  • US7422707B2 patent drawing
  • US7422707B2 patent drawing
  • US7422707B2 patent drawing

AI summary

A conductive composition for coating a semiconductor wafer comprises conductive filler that has an average particle size of less than 2 microns and a maximum particle size of less than 10 microns, a first resin that has a softening point between 80-260° C., solvent, curing agent, and a second resin, wherein at room temperature the first resin is substantially soluble in the solvent.