Conductive 1K Epoxy Adhesive for Low-Stress Solar Cell Connections

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Solution Overview

Problem

Conventional electrically conductive adhesives used in photovoltaic modules face challenges such as poor mechanical strength, high electrical contact resistance, and thermal stress due to coefficient of thermal expansion mismatches between materials, which affect the efficiency and longevity of solar cell connections.

Innovation Solution

A one-component epoxy adhesive composition incorporating a resin component with a first and second epoxy resin, a curative, electrically conductive filler, core-shell rubber toughener, and reactive diluent, optimized for high conductivity and mechanical strength, applied in shingled solar cell connections to reduce stress and enhance module efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional electrically conductive adhesives are used for solar cell connections, then electrical conductivity is achieved, but mechanical strength is poor

Engineering Contradiction:
Improvemechanical strengthVSAvoidconnection reliability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent employs a composite adhesive formulation combining epoxy resin with conductive filler particles (silver, aluminum, or carbon), creating a material that simultaneously provides mechanical bonding strength and electrical conductivity. The epoxy matrix contributes high mechanical strength and adhesion, while the conductive filler network ensures low electrical contact resistance, resolving the contradiction between mechanical strength and connection reliability.

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional conductive adhesives are used, then electrical connectivity is established, but electrical contact resistance is high

Engineering Contradiction:
Improveelectrical conductivityVSAvoidelectrical contact resistance
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent optimizes the concentration, size distribution, and morphology of conductive filler particles within the adhesive formulation. By controlling these parameters—specifically using 20-80 wt% conductive filler with optimized particle size distributions—the formulation achieves a percolation network that minimizes electrical contact resistance and reduces energy loss while maintaining electrical connectivity.

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If standard adhesive formulations are used, then bonding is achieved, but thermal stress resistance is poor due to coefficient of thermal expansion mismatches

Engineering Contradiction:
Improvethermal stabilityVSAvoidthermal stress
Core Design Contradiction:
Stability of the object's compositionVSStress or pressure

Solution Approach 1:

The patent modifies the adhesive formulation by incorporating functional additives and optimizing the resin-filler matrix composition to adjust the coefficient of thermal expansion (CTE) of the adhesive. This CTE matching between the adhesive and bonded substrates (solar cells and interconnectors) reduces differential thermal expansion, thereby minimizing thermal stress and improving thermal stability during temperature cycling.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If high filler content is used to improve conductivity, then electrical conductivity increases, but mechanical strength decreases

Engineering Contradiction:
Improveelectrical conductivityVSAvoidmechanical strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent employs a heterogeneous filler distribution strategy where conductive filler particles are non-uniformly distributed within the epoxy matrix. Higher filler concentrations are localized in regions requiring enhanced conductivity (near contact points), while other regions maintain lower filler content to preserve mechanical strength and adhesion properties. This spatial variation in filler quality resolves the contradiction between conductivity and strength.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition provides improved mechanical strength, reduced electrical contact resistance, and enhanced thermal stability, leading to increased efficiency and extended lifespan of photovoltaic modules by effectively managing thermal expansion and mechanical stresses.

Implementation Method 1

thermal stress due to coefficient of thermal expansion mismatches between materials

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Implementation Method 2

core-shell rubber particles

Methodology Applied
Scientific EffectElasticity: Elasticity

Implementation Method 3

electrically conductive particles

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 4

at least one epoxy resin and at least one epoxy functional reactive diluent

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Data Source

PatentUS20230386698A1Electrically conductive one component (1K) epoxy formulation
Publication Date: 2023.11.30 HENKEL KGAA
  • US20230386698A1 patent drawing
  • US20230386698A1 patent drawing
  • US20230386698A1 patent drawing

AI summary

The present invention is directed to an electrically conductive composition comprising: a) a resin component comprising: 1) a first epoxy resin; and, 2) a second epoxy resin and/or a functionalised polybutadiene resin and/or a functionalised butadiene-acrylonitrile copolymer; b) a curative for epoxy resin; c) an electrically conductive filler; d) a one core shell rubber toughener; and, e) a reactive diluent component comprising 1) a monofunctional epoxy diluent and/or 2) a polyfunctional epoxy diluent; wherein said composition further comprises a curing agent if said functionalised polybutadiene resin is present in said resin component.