Binder-Free Conductive Ink with Carbon Cage Architecture

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Solution Overview

Problem

Conductive inks for printing processes are expensive due to high metallic filler content and require high sintering temperatures, limiting substrate choices and causing pollution, while existing solutions fail to maintain high conductivity without polymer binders.

Innovation Solution

A binder-free conductive ink composition using metal powders and carbon powders as conductive cage architecture, with a solvent and dispersant, where carbon materials function as both conductive fillers and cage structures to trap metal particles, reducing metal content and enhancing conductivity through compression treatment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high metallic filler content is used in conductive ink, then conductivity is improved, but cost increases and oxidation problems occur

Engineering Contradiction:
ImproveconductivityVSAvoidmetal content
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent uses composite materials by combining metal powders with carbon powders (graphite, graphene, or carbon black) to create a conductive ink composition. The carbon components serve dual purposes: reducing the total metal content while maintaining conductivity and providing structural support. This composite approach allows the ink to achieve good electrical conductivity with lower metal loading, thereby reducing cost and oxidation susceptibility.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent introduces polymer resin binders as intermediary materials that facilitate the formation of continuous conductive networks. The binders hold the metal and carbon particles together, enabling efficient electron transport pathways while allowing reduced metal content. The resin matrix acts as a mediator that maintains structural integrity and conductivity without requiring high metal concentrations.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If high sintering temperature is used, then conductivity is improved, but substrate choices are limited

Engineering Contradiction:
ImproveconductivityVSAvoidsubstrate compatibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent changes the processing parameters by using low sintering temperatures (or alternative drying/curing methods) to process the conductive ink. The composition is specifically designed with polymer binders and carbon additives that enable effective conductivity at lower temperatures, thus expanding substrate compatibility to include temperature-sensitive materials that cannot withstand high sintering processes.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If traditional etching process is used, then conductivity is improved, but pollution and cost increase

Engineering Contradiction:
ImproveconductivityVSAvoidpollution
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent replaces the traditional mechanical etching process with a printing-based application method. Instead of using chemical etchants that create pollution, the invention uses screen printing or inkjet printing to deposit the conductive ink composition, followed by low-temperature sintering or drying. This substitution eliminates the need for harmful chemical etchants and their associated pollution while achieving comparable or superior conductivity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Strength

If polymer binders are added to conductive ink, then adhesion is improved, but conductivity decreases

Engineering Contradiction:
ImproveadhesionVSAvoidconductivity
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent uses composite materials by combining metal powders with carbon powders (graphite, graphene, or carbon black) to create a conductive ink composition. The carbon components serve dual purposes: reducing the total metal content while maintaining conductivity and providing structural support. This composite approach allows the ink to achieve good electrical conductivity with lower metal loading, thereby reducing cost and oxidation susceptibility.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent introduces polymer resin binders as intermediary materials that facilitate the formation of continuous conductive networks. The binders hold the metal and carbon particles together, enabling efficient electron transport pathways while allowing reduced metal content. The resin matrix acts as a mediator that maintains structural integrity and conductivity without requiring high metal concentrations.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The binder-free conductive ink achieves high conductivity and improved adhesion without the need for polymer binders, reducing metal content and eliminating high-temperature sintering, while maintaining low resistance and wide substrate compatibility.

Implementation Method 1

carbon powders, at least one dispersant, and a solvent. In fabrication process, post-compression treatment was carried to obtain good adhesion, high conductivity, and good performance antenna after the antenna printing

Methodology Applied
Scientific EffectPhysical containment: Physical Containment

Implementation Method 2

post-compression treatment was carried to obtain good adhesion, high conductivity, and good performance antenna after the antenna printing

Methodology Applied
Scientific EffectCompression: Compression

Implementation Method 3

a binder-free conductive ink composition, conductive cage architecture, and fabrication process for wireless antenna which decreases its metallic filler content of conductive ink but still maintains high conductivity

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Data Source

PatentUS10233346B2Conductive ink composition and conductive architecture for wireless antenna
Publication Date: 2019.03.19 LAI CHUNG PING
  • US10233346B2 patent drawing
  • US10233346B2 patent drawing

AI summary

A binder-free conductive ink with a conductive cage architecture for the wireless antenna with adhesion enhancement by carbon powders that aims to enormously reduce the solid content of conductor and can be used to print antennas. For example, silver content of the ink composition is greatly decreased due to the absence of insulated binder. Carbon powders (such as graphene nanoplatelets) are added as a conductive “cage” to reduce the use of insulated binder and significantly improve the conductivity of ink under low addition of conductor. Compression after printing is an innovative finding that not only improves the adhesion of a binder-free conductive ink with a conductive cage architecture but also enhances its conductivity. Such effects are credited to excellent contact between interfaces of particles and substrate. The unique recipe and process save printing from high-temperature sintering, further reducing processing cost and widening applicable substrates.