Conductive Polymer Electrodes for Transparent Light-Emitting Devices

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Solution Overview

Problem

Existing light-emitting devices and photovoltaic cells face challenges in achieving high electric conductivity while maintaining thin electrode thickness, which affects transparency and brightness, and are costly due to increased material usage and complex vacuum-based deposition methods.

Innovation Solution

A light-emitting device and photovoltaic cell design featuring a cathode and anode with a conductive material having an aspect ratio of 1.5 or more, and an electron injection layer containing organic compounds with ionic or polar groups, fabricated using a coating method at normal pressure, allowing for improved conductivity and transparency without the need for thick electrodes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the thickness of the electrode is increased to achieve higher electric conductivity, then the electric conductivity is improved, but the transparency of the emitting light is reduced and the manufacturing cost increases

Engineering Contradiction:
Improveelectric conductivityVSAvoidtransparency of emitting light
Core Design Contradiction:
ReliabilityVSIllumination intensity

Solution Approach 1:

The patent changes the physical and chemical parameters of the electrode material by using conductive polymers with optimized molecular structure, doping levels, and composition ratios. This allows achieving high conductivity without increasing thickness, thus maintaining transparency. The conductive polymer materials have adjustable parameters including carrier concentration, mobility, and band gap that can be tuned to balance conductivity and optical properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite electrode structures combining conductive polymers with other materials such as metal nanoparticles, carbon materials, or inorganic conductive oxides. This composite approach synergistically enhances electrical conductivity while maintaining optical transparency, as the different components contribute different properties - the polymer provides flexibility and processability while the additives boost conductivity without requiring thick layers.

Inventive Principle:
Principle #40Composite materials

2Reliability

If the thickness of the electrode is increased to achieve higher electric conductivity, then the electric conductivity is improved, but the manufacturing cost becomes high due to increased material usage

Engineering Contradiction:
Improveelectric conductivityVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

By optimizing the parameters of conductive polymer materials including molecular weight, doping concentration, and blend ratios, the patent achieves high conductivity at reduced material thickness. This parameter optimization reduces the amount of expensive materials required while maintaining performance, directly lowering manufacturing costs.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses conductive polymers that can be processed from solution and deposited as thin films, replacing expensive and scarce metals like indium (in ITO). These polymer-based electrodes are cheaper, more abundant, and can be manufactured using low-cost solution processing techniques, reducing both material and equipment costs.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Reliability

If a deposition method is used to form metal layers or alloy layers, then the electron injection characteristic is improved, but the manufacturing process loses continuity and productivity decreases

Engineering Contradiction:
Improveelectron injection characteristicVSAvoidmanufacturing continuity
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent replaces the mechanical vacuum deposition system with a solution-based coating process. The conductive polymer electrode materials are dissolved in solvents to form ink solutions that can be deposited using simple techniques such as spin coating, dip coating, or spray coating. This substitution eliminates the need for vacuum equipment and allows continuous processing, dramatically improving productivity while maintaining electron injection performance through proper material design.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent employs liquid-based delivery systems to transport and deposit electrode materials. The conductive polymer solutions can be pumped and sprayed continuously onto substrates, enabling high-speed manufacturing processes. This hydraulic approach replaces the thermal field-based vacuum deposition with a fluid-based process that is more suitable for continuous production.

Inventive Principle:
Principle #29Pneumatics and hydraulics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enhances electric conductivity, transparency, and electron injection characteristics, leading to improved light-emitting brightness and photovoltaic efficiency while reducing manufacturing costs and complexity by eliminating the need for vacuum-based deposition.

Implementation Method 1

at least one of the cathode and the anode comprises a conductive material having an aspect ratio of 1.5 or more

Methodology Applied
Scientific EffectAnisotropic conduction:

Implementation Method 2

the electron injection layer comprises an organic compound having at least one of an ionic group and a polar group

Methodology Applied
Scientific EffectElectron injection:

Implementation Method 3

the electron injection layer comprises an organic compound having at least one of an ionic group and a polar group

Methodology Applied
Scientific EffectIonic interaction: Ion Repulsion/Attraction

Implementation Method 4

fabricated using a coating method at normal pressure

Methodology Applied
Scientific EffectCoating deposition: Coatings

Data Source

PatentUS8866134B2Light-emitting device and photovoltaic cell, and method for manufacturing the same
Publication Date: 2014.10.21 SUMITOMO CHEM CO LTD
  • US8866134B2 patent drawing
  • US8866134B2 patent drawing
  • US8866134B2 patent drawing

AI summary

Provided are a light-emitting device and a photovoltaic cell having excellent characteristics. A light-emitting device (10) includes a cathode (34), an anode (32), a light-emitting layer (50) interposed between the cathode (34) and the anode (32), and an electron injection layer (44) provided between the cathode (34) and the light-emitting layer (50) and connected to the cathode (34), in which at least one of the anode (32) and the cathode (34) contains a conductive material having an aspect ratio of 1.5 or more, and the electron injection layer (44) contains an organic compound having at least one of an ionic group and a polar group.