Thermally Stable Conductive Polymers for Gas Sensors

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Solution Overview

Problem

Conventional electrochemical gas sensors face issues with size, thermal stability, signal-to-noise ratio, and compatibility with high-temperature soldering processes, limiting their reliability and portability, especially in applications requiring compact, low-power, and fast response sensors.

Innovation Solution

The use of thermally stable conductive aromatic polymers with aromatic groups containing nitrogen, infused in an inorganic acid, which form the basis for membrane electrode assemblies that provide enhanced thermal stability and conductivity, enabling compact, low-energy consumption, and high-temperature resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If conventional polymer electrolytes are used in electrochemical gas sensors, then the sensors can be manufactured with standard materials, but the sensors cannot withstand temperatures above 150°C and cannot survive solder reflow processes

Engineering Contradiction:
Improvethermal stabilityVSAvoidsurvival during soldering
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent uses a composite material consisting of an aromatic polymer backbone (providing thermal stability) infused with inorganic acid (providing ionic conductivity). This composite structure allows the electrolyte to withstand temperatures up to 280°C while maintaining electrochemical functionality, enabling direct soldering without damage.

Inventive Principle:
Principle #40Composite materials

2Volume of moving object

If the sensor size is reduced for portability, then the sensor becomes more suitable for portable devices, but the stabilization time increases and signal-to-noise ratio decreases

Engineering Contradiction:
Improvesensor sizeVSAvoidstabilization time
Core Design Contradiction:
Volume of moving objectVSLoss of time

Solution Approach 1:

The patent changes the physical and chemical parameters of the electrolyte by using a highly conductive inorganic acid-infused aromatic polymer. This increases ionic conductivity and reduces electrolyte volume, enabling compact sensor design with fast response times and high signal-to-noise ratio despite reduced size.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional electrolytes are used, then the manufacturing process is simple, but additional protective measures are needed that increase sensor size and power consumption

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidsensor size
Core Design Contradiction:
Ease of manufactureVSVolume of moving object

Solution Approach 1:

The patent changes the thermal parameter of the electrolyte material to withstand soldering temperatures directly. This eliminates the need for additional protective measures such as thermal barriers or indirect mounting techniques, simplifying the manufacturing process while maintaining compact sensor size.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in electrochemical gas sensors that maintain stability and functionality across a wide temperature range, including solder reflow temperatures, and improve signal quality and sensor compactness, addressing the limitations of conventional sensors.

Implementation Method 1

thermally stable conductive aromatic polymers with aromatic groups containing nitrogen, infused in an inorganic acid

Methodology Applied
Scientific EffectIonic conduction: Conduction (electrical)

Implementation Method 2

measuring the concentration of a target gas by oxidizing or reducing the gas at an electrode and measuring the resulting current

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 3

measuring the concentration of a target gas by oxidizing or reducing the gas at an electrode and measuring the resulting current

Methodology Applied
Scientific EffectReduction: Reduction

Data Source

PatentUS11453749B2Thermally stable conductive polymers for electrochemical gas sensor applications
Publication Date: 2022.09.27 ADVENT TECHNOLOGIES HOLDINGS INC
  • US11453749B2 patent drawing
  • US11453749B2 patent drawing
  • US11453749B2 patent drawing

AI summary

Aromatic polymers exhibiting thermal stability and conductivity upon imbibement into an acid are disclosed for electrochemical gas sensor applications. Membrane electrode assemblies for electrochemical gas sensors are also provided, comprising a sensing electrode, a counter electrode, and a polymer membrane comprising the polymers of the present invention, disposed between the sensing electrode and the counter electrode.