Conductive Polymer Layer Structuring via Protective Masking

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Solution Overview

Problem

Existing methods for structuring electrically conductive polymer layers, such as those based on polythiophenes, face challenges in achieving uniform conductivity reduction without affecting layer thickness or color, often resulting in irregularities that impact electrical properties and appearance.

Innovation Solution

A process involving a layered body with a substrate and an electrically conductive polymer layer, where a covering layer is applied to specific regions to reduce conductivity and then partially removed using an alkaline aqueous treatment, allowing for sharp transitions between conductive and reduced conductivity areas without significant color changes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional structuring methods (etching, printing) are used to reduce conductivity in specific regions, then conductivity is reduced, but layer thickness becomes irregular and color changes occur

Engineering Contradiction:
Improveconductivity reduction uniformityVSAvoidlayer thickness uniformity
Core Design Contradiction:
Manufacturing precisionVSShape

Solution Approach 1:

A covering layer is applied in advance to the regions where conductivity should be maintained, protecting these areas during subsequent etching treatment. This preliminary protective action prevents the etching solution from affecting the underlying conductive polymer layer in the covered regions, thereby maintaining uniform thickness and color while achieving conductivity reduction only in uncovered areas.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The covering layer acts as an intermediary substance between the etching solution and the conductive polymer layer. It selectively allows the etching solution to access and reduce conductivity in specific regions while blocking access to protected regions, thus enabling precise conductivity control without compromising layer integrity or appearance.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If etching solutions are used to structure conductive polymer layers, then conductivity is reduced, but the color and appearance of the layer are adversely affected

Engineering Contradiction:
Improveconductivity structuringVSAvoidcolor change
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The covering layer is applied before etching to pre-protect regions where color and appearance must be maintained. This preliminary protective measure ensures that the etching solution only contacts the conductive polymer in regions where conductivity reduction is desired, preventing unwanted color changes in protected areas.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The covering layer serves as a protective intermediary that selectively shields the conductive polymer layer from the etching solution. By controlling which regions are exposed to the etching solution, the covering layer prevents harmful color changes in protected regions while allowing necessary conductivity reduction in uncovered regions.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If printing processes are used to apply structured conductive layers, then conductivity is achieved in specific regions, but the outer region of drops is thicker than the inner region causing irregularity

Engineering Contradiction:
Improveconductivity distributionVSAvoidlayer thickness uniformity
Core Design Contradiction:
Manufacturing precisionVSShape

Solution Approach 1:

Instead of applying conductive material in a structured manner that causes thickness irregularities, the invention applies a uniform covering layer first, then uses etching to create the desired conductivity pattern. This reverse approach ensures uniform layer thickness is maintained while achieving precise conductivity control through selective removal of the covering layer and underlying polymer.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process effectively reduces conductivity in targeted regions while maintaining the original color and thickness of the layer, achieving sharp transitions and improved electrical properties.

Implementation Method 1

a covering layer is applied to specific regions to reduce conductivity and then partially removed using an alkaline aqueous treatment

Methodology Applied
Scientific EffectAlkaline treatment:

Data Source

PatentUS10671192B2Process for the production of a layered body and layered bodies obtainable therefrom
Publication Date: 2020.06.02 HERAEUS EPURIO GMBH
  • US10671192B2 patent drawing
  • US10671192B2 patent drawing
  • US10671192B2 patent drawing

AI summary

Described is a process for the production of a layered body S2 comprising:i. provision of a layered body S1 comprising a substrate and an electrically conductive layer which is applied to the substrate and comprises an electrically conductive polymer P1;ii. partial covering of a part of the electrically conductive layer with a covering layer D, comprising a polymer P2 contained therein, from a covering phase to obtain at least one covered region Dd and at least one non-covered region Du of the electrically conductive layer;iii. reduction of the electrical conductivity of the electrically conductive layer in at least a part of the at least one non-covered region Du compared with the electrical conductivity of the electrically conductive layer in the at least one covered region Dd;iv. at least partial removal of the covering layer D by an alkaline aqueous treatment.