Conductive Polymer Separator for Solid Electrolytic Capacitors

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Solution Overview

Problem

Conventional solid electrolytic capacitors with a conductive polymer electrolyte have low dielectric oxide film repair capability, leading to increased leak current and short-circuit failures due to defects, making it difficult to achieve high withstand voltage.

Innovation Solution

An electrical storage device with a conductive separator having a specific surface layer configuration, where the anode-facing surface lacks conductive polymer and the cathode-facing surface is coated with it, allowing for efficient impregnation of an electrolytic solution to enhance dielectric oxide film repair and reduce equivalent series resistance (ESR).

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If a solid electrolyte made of conductive polymer is used, then ESR is reduced, but dielectric oxide film repair capability deteriorates leading to increased leak current and short-circuit failures

Engineering Contradiction:
ImproveESRVSAvoiddielectric oxide film repair capability
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The electrolyte is segmented into two distinct components: a solid electrolyte (conductive polymer) and a liquid electrolyte. The solid electrolyte is applied to the separator to reduce ESR, while the liquid electrolyte is impregnated into the separator to provide dielectric oxide film repair capability. This segmentation allows each component to fulfill its specific function without compromising the other.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses a composite electrolyte system combining solid and liquid electrolytes. The separator contains both conductive polymer (solid) and liquid electrolyte, creating a composite structure that exhibits both low ESR characteristics and high dielectric oxide film repair capability. This composite approach resolves the contradiction by integrating the advantages of both material types.

Inventive Principle:
Principle #40Composite materials

2Loss of energy

If only solid electrolyte is used, then ESR is reduced, but leak current increases due to low dielectric oxide film repair capability

Engineering Contradiction:
ImproveESRVSAvoidleak current
Core Design Contradiction:
Loss of energyVSObject-generated harmful factors

Solution Approach 1:

The electrolyte system is segmented into solid and liquid components with distinct functions. The solid electrolyte (conductive polymer) addresses ESR reduction, while the liquid electrolyte specifically addresses leak current reduction through its superior dielectric oxide film repair capability. This functional segmentation eliminates the harmful effect of high leak current while maintaining low ESR.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The liquid electrolyte acts as an intermediary that mediates between the solid electrolyte and the dielectric oxide film. It provides the chemical environment necessary for repairing dielectric oxide film defects, thereby reducing leak current, while the solid electrolyte provides the conductive pathway for low ESR operation.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The configuration improves the withstand voltage characteristic and reduces ESR, effectively addressing the limitations of conventional solid electrolytic capacitors by ensuring better dielectric film repair and conductivity.

Implementation Method 1

a conductive polymer adhering to the separator substrate

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

The electrical storage element is impregnated with the electrolytic solution

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 3

a conductive polymer that has an electric conductivity higher than that of a conventional electrolytic solution

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Data Source

PatentUS10431392B2Electrical storage device, manufacturing method of the same, and separator
Publication Date: 2019.10.01 PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD
  • US10431392B2 patent drawing
  • US10431392B2 patent drawing
  • US10431392B2 patent drawing

AI summary

An electrical storage device includes an electrical storage element and an electrolytic solution. The electrical storage element is formed of an anode body, a cathode body facing the anode body, and a separator interposed between the anode body and the cathode body. The separator includes a separator substrate and a conductive polymer adhering to the separator substrate. The electrical storage element is impregnated with the electrolytic solution. The separator includes a first surface layer having a first surface facing the anode body and a second surface layer having a second surface facing the cathode body. The first surface layer includes a first region that is not provided with the conductive polymer, and the second surface layer includes a second region provided with the conductive polymer.