Conductive Core-Shell Proppant Pellets for Shape and Strength Control

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Solution Overview

Problem

Existing carbon-based proppants for hydraulic fracturing suffer from irregular shape, low density, weak-moderate strength, broad size distributions, and bulk scale availability, which hinder effective electrical conductivity and fracture imaging.

Innovation Solution

A method to produce electrically-conductive pellets by reducing and wetting carbon-based materials to form a core-shell structure, using a fluidizer to create green pellets, and applying a conductive shell layer, followed by drying and calcining to achieve specific size, density, and conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If carbon-based materials are used as proppant, then electrical conductivity is improved, but shape regularity deteriorates

Engineering Contradiction:
Improveelectrical conductivityVSAvoidshape regularity
Core Design Contradiction:
ReliabilityVSShape

Solution Approach 1:

The patent combines carbon-based materials (coke breeze, graphite) with ceramic materials (alumina, silica) to create composite proppant particles. The ceramic matrix provides regular spherical shape and mechanical strength, while the carbon additive (5-50 wt%) provides electrical conductivity for electromagnetic imaging. This composite approach resolves the contradiction by integrating materials with complementary properties.

Inventive Principle:
Principle #40Composite materials

2Reliability

If carbon-based materials are used as proppant, then electrical conductivity is improved, but strength deteriorates

Engineering Contradiction:
Improveelectrical conductivityVSAvoidcrush strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent creates composite proppants where ceramic materials (alumina, silica) form the structural matrix providing high crush strength (10-50 kpsi), while carbon-based materials (coke breeze, graphite powder) are incorporated at 5-50 wt% to provide electrical conductivity. The ceramic framework maintains mechanical integrity while the carbon phase enables electromagnetic imaging functionality.

Inventive Principle:
Principle #40Composite materials

3Reliability

If carbon-based materials are used as proppant, then electrical conductivity is improved, but density deteriorates

Engineering Contradiction:
Improveelectrical conductivityVSAvoidbulk density
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent formulates composite proppants where high-density ceramic materials (alumina density 3.95 g/cm³, silica density 2.65 g/cm³) serve as the primary matrix, achieving bulk densities of 80-120 lbs/cu ft. Carbon-based materials (coke breeze density 1.8-2.2 g/cm³, graphite density 2.2 g/cm³) are added at 5-50 wt% to provide electrical conductivity with minimal impact on overall density, as the carbon phase fills void spaces and coats particle surfaces.

Inventive Principle:
Principle #40Composite materials

4Reliability

If carbon-based materials are used as proppant, then electrical conductivity is improved, but size distribution control deteriorates

Engineering Contradiction:
Improveelectrical conductivityVSAvoidsize distribution
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent employs a multi-stage size control process: (1) Crushing carbon-based materials to target size ranges, (2) Classifying particles through screening and separation equipment, (3) Mixing with ceramic materials of complementary size distributions, and (4) Final sizing through controlled crushing and classification. This segmented approach achieves narrow size distributions (e.g., 40/70 mesh, 50/100 mesh) while maintaining electrical conductivity through proper carbon content distribution.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The pellets exhibit improved shape, strength, density, and electrical conductivity, enhancing fracture imaging and packing efficiency, and are suitable for use in hydraulic fracturing applications.

Implementation Method 1

introducing the first slurry into a fluidizer to produce a first pellet

Methodology Applied
Scientific EffectFluidization: Fluidisation

Implementation Method 2

drying

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 3

Calcining increases the electrical conductivity (e.g., 1,000 S/m@150 psi) and also increases the hardness and density of the particles

Methodology Applied
Scientific EffectCalcining: Heat Treatment

Data Source

PatentUS12502649B2Composition and process for pelletizing carbon-based materials for proppant and industrial applications
Publication Date: 2025.12.23 CARBO CERAMICS INC
  • US12502649B2 patent drawing
  • US12502649B2 patent drawing
  • US12502649B2 patent drawing

AI summary

A method for producing an electrically-conductive pellet includes reducing a size of a first material. The method also includes wetting the first material to produce a first slurry. The method also includes introducing the first slurry into a fluidizer to produce a first pellet. The method also includes reducing a size of a second material. The second material is an electrically-conductive material. The method also includes wetting the second material to produce a second slurry. The method also includes applying the second slurry to the first pellet.