Conductive Sealant Compositions for EMI Shielding

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Solution Overview

Problem

Aircraft face risks from lightning strikes and electromagnetic interference (EMI) that can cause physical damage and operational difficulties, with existing technologies failing to effectively mitigate these issues through adequate EMI/RFI shielding.

Innovation Solution

A sealant composition incorporating a sulfur-containing polymer, a curing agent, and electrically conductive fillers such as carbon nanotubes and stainless steel fibers, which are blended to form a conductive matrix that provides superior EMI/RFI shielding effectiveness while being substantially nickel-free.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional conductive fillers containing nickel are used, then electrical conductivity is achieved, but toxicity concerns and health risks arise

Engineering Contradiction:
ImproveEMI/RFI shielding effectivenessVSAvoidnickel toxicity
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent employs a composite filler system combining carbon nanotubes with stainless steel fibers (grades 304, 316, or 316L) to achieve EMI/RFI shielding without nickel. This composite approach leverages the high aspect ratio and conductivity of stainless steel fibers alongside the nanoscale conductivity of carbon nanotubes, creating a synergistic effect that provides superior shielding effectiveness while eliminating toxic nickel content entirely

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention changes the compositional parameters of the conductive filler by specifying stainless steel grades 304, 316, or 316L which contain chromium and nickel-stabilizing elements but are formulated to be substantially nickel-free or low-nickel. This parameter change maintains electrical conductivity and shielding effectiveness while reducing or eliminating the harmful nickel toxicity associated with conventional fillers

Inventive Principle:
Principle #35Parameter changes

2Reliability

If carbon nanotubes and stainless steel fibers are used as fillers, then EMI/RFI shielding effectiveness is improved, but formulation complexity increases

Engineering Contradiction:
ImproveEMI/RFI shielding effectivenessVSAvoidformulation complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent specifies precise parameter ranges for the filler components: carbon nanotubes with aspect ratios of 10:1 to 100:1 and stainless steel fibers with length diameters of 10 μm to 100 μm and width diameters of 1 μm to 10 μm. These parameter specifications optimize the percolation threshold and conductivity network formation, achieving effective shielding while providing clear formulation guidance that reduces complexity through defined parameters rather than open-ended composition

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The sealant composition exhibits unexpectedly superior EMI/RFI shielding effectiveness, reducing the risks associated with lightning strikes and electromagnetic interference, and eliminates the toxicity concerns associated with nickel in conventional conductive fillers.

Implementation Method 1

The electrically conductive filler includes carbon nanotubes and stainless steel fibers... exhibits unexpectedly superior EMI/RFI shielding effectiveness

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Data Source

PatentUS9484123B2Conductive sealant compositions
Publication Date: 2016.11.01 PRC DESOTO INTERNATIONAL INC

AI summary

Embodiments of the present disclosure are directed to sealant compositions including a base composition with at least one sulfur-containing polymer, a curing agent composition, and an electrically conductive filler including carbon nanotubes and stainless steel fibers. The electrically conductive filler can be in either or both of the base composition and the curing agent composition. The sealant compositions are substantially Ni-free and exhibit unexpectedly superior EMI/RFI shielding effectiveness.