Conformal Solid State Doping for Source/Drain Contact Resistance

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Solution Overview

Problem

The increasing contact resistance in smaller CMOS and NMOS devices due to smaller contact areas poses a challenge, particularly for FinFET and nanowire devices, where traditional ion implantation methods are difficult to implement effectively.

Innovation Solution

The use of atomic layer deposition (ALD) for conformal solid state doping (SSD) to form dopant layers in source/drain regions, which includes surface cleaning, deposition of a dopant layer, a capping layer, and a drive-in anneal step to achieve precise sub-nanometer thickness control and ultra-shallow doping profiles, thereby improving contact resistivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional ion implantation is used to achieve high source/drain doping, then contact resistance can be reduced, but the process becomes difficult to implement effectively in FinFET and nanowire devices

Engineering Contradiction:
Improvecontact resistanceVSAvoiddoping process implementation
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent replaces the mechanical ion implantation process with a chemical deposition process (atomic layer deposition or chemical vapor deposition) to deliver dopants to the source/drain regions. This substitution enables effective doping in three-dimensional structures like FinFETs and nanowires where ion implantation is difficult to implement, while still achieving the required doping levels to reduce contact resistance

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the doping method from physical ion implantation to chemical deposition, and further optimizes by using conformal deposition techniques with controlled thickness parameters. This allows precise control of dopant distribution and concentration in complex three-dimensional geometries, achieving both low contact resistance and ease of manufacture

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If conformal solid state doping is used to achieve precise sub-nanometer thickness control, then doping precision is improved, but process complexity increases

Engineering Contradiction:
Improvedoping profile controlVSAvoiddoping process steps
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent segments the doping process into distinct sequential steps: surface preparation/cleaning, conformal dopant layer deposition via atomic layer deposition or chemical vapor deposition, and thermal annealing for dopant activation and diffusion. This segmentation enables precise control of each step independently, achieving sub-nanometer thickness control while managing process complexity through systematic breakdown

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent performs preliminary surface cleaning and preparation steps before dopant deposition to ensure optimal adhesion and uniformity. The conformal dopant layer is deposited with precise thickness control before the thermal annealing step, ensuring that the doping profile is established with the required precision before activation, thereby achieving high manufacturing precision

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method achieves a significantly higher doping level (up to 5×10^20/cm^3) with minimal defect formation and morphology degradation, enhancing the performance of source/drain regions in CMOS and NMOS devices by providing conformal 3-D doping and precise control over dopant distribution.

Implementation Method 1

performing an atomic layer deposition of a dopant layer on the substrate

Methodology Applied
Scientific EffectAtomic layer deposition: Chemical Vapour Deposition

Implementation Method 2

performing a drive-in anneal step—to diffuse dopant from the dopant layer into the at least one formed source/drain region

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 3

performing a surface cleaning on the substrate, the surface cleaning removing oxides or native oxides from the substrate

Methodology Applied
Scientific EffectOxide removal:

Data Source

PatentUS10665452B2Source/drain performance through conformal solid state doping
Publication Date: 2020.05.26 ASM IP HLDG BV
  • US10665452B2 patent drawing
  • US10665452B2 patent drawing
  • US10665452B2 patent drawing

AI summary

A method for improving source/drain performance through conformal solid state doping and its resulting device are disclosed. Specifically, the doping takes place through an atomic layer deposition of a dopant layer. Embodiments of the invention may allow for an increased doping layer, improved conformality, and reduced defect formation, in comparison to alternate doping methods, such as ion implantation or epitaxial doping.