Silicone Hydrogel Contact Lens Marking via UV Curing

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Solution Overview

Problem

Existing methods for marking contact lenses, such as printing and laser marking, face issues with durability and readability, leading to reduced mechanical strength and comfort due to dye flow-off, discoloration, or laser ablation, necessitating a method for silicone hydrogel contact lenses with identifying marks that maintain comfort and mechanical integrity.

Innovation Solution

A method involving a mold assembly with a silicone-containing polymer binder ink, partially cured with high-intensity UV light, followed by exposure of mold surfaces to a second UV light before filling with a silicone-containing vinylic monomer and hydrophilic monomer, ensuring high ion permeability and clear or colored identifying marks that adhere well without smudging or delamination.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional printing method with dyestuff in organic medium is used, then identifying marks can be applied to contact lens surfaces, but the dyestuffs may be flowed off, discolored, or peeled off due to repeated cleaning and disinfection treatments

Engineering Contradiction:
Improvemarking processVSAvoidmark durability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent changes the chemical parameters of the marking medium by replacing organic solvent-based dyestuffs with water-soluble or water-dispersible dyestuffs. This parameter change allows the marks to remain stable during repeated cleaning and disinfection treatments while maintaining ease of application through printing methods.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite material systems combining water-soluble/dispersible dyestuffs with specific binders or polymers that provide adhesion to the contact lens surface. This composite approach ensures both the ease of application and the durability against flow-off, discoloration, and peeling during repeated treatments.

Inventive Principle:
Principle #40Composite materials

2Reliability

If laser radiation marking method is used, then identifying marks can be printed or engraved on lens or mold, but the lens material is ablated or thickness is reduced, reducing mechanical strength

Engineering Contradiction:
Improvemark readabilityVSAvoidmechanical strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent replaces the mechanical/thermal laser ablation process with a chemical deposition process using water-soluble or water-dispersible dyestuffs. This substitution eliminates material removal and associated strength reduction while maintaining mark readability through conventional printing methods applied to the lens surface or mold.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Reliability

If high intensity UV light is used to cure identifying mark coat, then mark adhesion and durability are improved, but lens material may be affected by UV exposure

Engineering Contradiction:
Improvemark adhesionVSAvoidUV light effect on lens material
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent applies local quality by using water-soluble or water-dispersible dyestuffs specifically in the marking areas rather than throughout the entire lens material. This localized approach allows UV curing to be applied to enhance mark adhesion and durability without subjecting the bulk lens material to harmful UV effects, as the dyestuffs are confined to specific surface regions.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method achieves high-quality, durable identifying marks on silicone hydrogel contact lenses with enhanced ion permeability and mechanical strength, preventing smudging and delamination, while maintaining lens comfort and clarity.

Implementation Method 1

irradiating the identifying mark coat on the molding surface with a first high intensity UV light to at least partially cure the identifying mark coat

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Implementation Method 2

irradiating the exposed surfaces of the female mold half and the male mold half with a second high intensity UV light prior to filling a lens-forming fluid material

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Implementation Method 3

exposing the mold assembly and the lens-forming fluid material to an energy source, wherein the energy source polymerizes the lens-forming fluid material

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Data Source

PatentEP2797735B1Method of making contact lenses with identifying mark
Publication Date: 2016.04.06 NOVARTIS AG
  • EP2797735B1 patent drawing
  • EP2797735B1 patent drawing
  • EP2797735B1 patent drawing

AI summary

The present invention is related to a method for making silicone hy- drogel contact lenses with an identifying mark, by irradiating the iden¬ tifying mark coat on the molding surface with a first and a second high intensity UV light prior to filling the lens-forming fluid material; exposing the mold assembly and the lens-forming fluid material to an energy source which polymerizes the lens-forming fluid materi¬ al wherein the emission spectrum of the first high intensity UV light has a higher intensity in the wavelength range of 320-390 nm by at least 200 mW/cm<2> and a lower intensity in the wavelength range of 250-260 nm by at least 10 mW/cm<2> than the second high inten¬ sity UV light.