Continuous Catalyst Replacement in Reforming Reactors

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Solution Overview

Problem

Reforming processes face significant downtime and economic burdens due to catalyst deactivation, requiring frequent shutdowns for catalyst replacement and mandatory inspections, which can last from thirty to sixty days and incur substantial costs.

Innovation Solution

A continuous reforming process is implemented using a series of reactors where a spent catalyst is isolated, restored, and then reintegrated into the series in a different order, allowing for continuous operation without complete shutdowns, and potentially eliminating the need for a sulfur removal system by reordering reactors to optimize catalyst activity and efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If catalyst replacement is performed to restore reforming process efficiency, then catalyst activity is improved, but complete process shutdown is required causing production loss

Engineering Contradiction:
Improvecatalyst activityVSAvoidproduction continuity
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The reforming process is divided into multiple reactor units (first reactor, second reactor, third reactor) that can operate independently or in series. This segmentation allows one reactor to be taken offline for catalyst replacement while others continue operating, eliminating the need for complete process shutdown and maintaining production continuity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The system employs dynamic flow distribution through valves and bypass lines that can be reconfigured to route hydrocarbon streams through different reactor combinations. This dynamic flexibility enables seamless transition between operational modes during catalyst replacement, maintaining continuous production while restoring catalyst activity in isolated units.

Inventive Principle:
Principle #15Dynamics

2Productivity

If multiple reactors are used to enable continuous operation, then production continuity is improved, but system complexity increases

Engineering Contradiction:
Improvecontinuous operationVSAvoidreactor system configuration
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

Each reactor unit is designed with identical or similar functionality, equipped with its own furnace, catalyst bed, and associated valve/bypass infrastructure. This universal design allows any reactor to replace another in the flow sequence, simplifying operational procedures despite having multiple units, as each component serves the same purpose and can be interchanged without complex reconfiguration.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Loss of time

If catalyst is restored in-situ to reduce shutdown time, then replacement time is reduced, but catalyst restoration capability must be maintained

Engineering Contradiction:
Improvecatalyst replacement timeVSAvoidrestoration system requirements
Core Design Contradiction:
Loss of timeVSDevice complexity

Solution Approach 1:

The catalyst bed is designed to be extractable from the reactor vessel while the reactor itself remains in service. This extraction capability allows spent catalyst to be removed and replaced with fresh or regenerated catalyst without taking the reactor offline for extended periods, significantly reducing catalyst replacement time while maintaining relatively simple restoration infrastructure.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables continuous operation of the reforming process, extends catalyst life, reduces production losses, and simplifies the process by eliminating the need for a sulfur removal system, thereby saving costs and improving operational flexibility.

Implementation Method 1

each reactor contains a catalyst; each reactor comprises a reforming catalyst; a catalyst capable of converting at least a portion of a hydrocarbon stream to aromatic hydrocarbons

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentEP2771432B1System and method for on stream catalyst replacement
Publication Date: 2021.07.14 CHEVRON PHILLIPS CHEMICAL COMPANY LP
  • EP2771432B1 patent drawingFigure 1
  • EP2771432B1 patent drawingFigure 2
  • EP2771432B1 patent drawingFigure 3

AI summary

A process for operating a reforming reactor system comprising operating a plurality of reactors until at least one reactor is deemed to have an operational issue, wherein each of the plurality of reactors contains a catalyst capable of converting at least a portion of a hydrocarbon stream to aromatic hydrocarbons, isolating the at least one reactor deemed to have the operational issue from a remaining plurality of reactors that continue to operate to convert at least the portion of the hydrocarbon stream to aromatic hydrocarbons while the at least one reactor deemed to have the operational issue is isolated from the plurality of remaining reactors, addressing the operational issues, returning the at least one reactor to the hydrocarbon stream by connecting the reactor to the remaining plurality of reactors, and resuming operations of the reforming reactor system to convert at least the portion of the hydrocarbon stream to aromatic hydrocarbons.