Continuous Flow Mixer With Offset Channels to Reduce Compositional Noise

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Solution Overview

Problem

Existing fluid chromatography systems face challenges in efficiently mixing fluids under laminar flow conditions, leading to compositional noise and reduced precision in sample quantification due to pump-induced discontinuities, which are not effectively addressed by current mixers that either increase volume or are prone to contamination and clogging.

Innovation Solution

A continuous flow mixer with a radially or axially symmetric channel structure that splits fluid flow into multiple branches, utilizing volume offsets and concentric stages to evenly distribute and recombine fluid flow, thereby reducing compositional ripple and enhancing mixing efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If large volume mixers are used to achieve effective mixing, then mixing performance is improved, but testing time increases and throughput diminishes

Engineering Contradiction:
Improvemixing performanceVSAvoidthroughput
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The mixer divides the fluid flow into multiple parallel channels (first and second inlet branches with multiple outlet branches each), allowing mixing to occur simultaneously across multiple pathways. This segmented approach achieves effective mixing without requiring a single large volume chamber, thereby maintaining throughput while improving mixing performance.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention transitions from traditional single-dimension mixing (sequential passage through a large chamber) to multi-dimensional mixing by creating a network of parallel channels with offset residence times. Fluids are mixed across spatial dimensions through the channel network rather than through temporal accumulation in a large volume, reducing delay volume while maintaining mixing effectiveness.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Reliability

If packed-bead LC mixers are used for mixing, then mixing can be achieved, but they are inefficient relative to delay volume, difficult to manufacture, and prone to contamination and clogging

Engineering Contradiction:
Improvemixing capabilityVSAvoidmanufacturing difficulty
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The invention extracts the mixing function from the complex packed-bead structure and implements it through a simplified channel network geometry. By removing the packed beads and replacing them with defined channels featuring offset residence times, the design achieves mixing capability while eliminating manufacturing complexity and contamination risks associated with packed structures.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention replaces the porous packed-bead structure with non-porous channel walls, eliminating the porosity-related issues of clogging and contamination while maintaining the flow distribution and mixing functions. The channel network provides defined flow paths without requiring porous materials.

Inventive Principle:
Principle #31Porous materials

3Power

If pumps deliver flow in discrete strokes, then positive displacement pumping is achieved, but compositional discontinuities cause noise and decrease precision in sample quantification

Engineering Contradiction:
Improvepumping capabilityVSAvoidsample quantification precision
Core Design Contradiction:
PowerVSMeasurement precision

Solution Approach 1:

The mixer performs preliminary mixing action within each pump stroke by distributing fluid through multiple channels with offset residence times before the composition discontinuity occurs. This preliminary mixing smooths compositional variations within the stroke, reducing the amplitude of compositional ripples that would otherwise propagate through the system and degrade measurement precision.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention utilizes the periodic nature of pump strokes by designing channels with residence times synchronized to the pump frequency. The offset residence times create a periodic mixing pattern that counteracts the periodic compositional discontinuities introduced by the pump strokes, effectively canceling out the noise at the pump frequency and its harmonics.

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The mixer effectively cancels or reduces unwanted compositional oscillations, improving precision and throughput by minimizing pressure drop and delay volume, while being easy to manufacture and less susceptible to contamination.

Implementation Method 1

mixers require creative designs to promote controlled dispersion

Methodology Applied
Scientific EffectControlled dispersion: Diffusion

Data Source

PatentEP4217729B1Continuous flow mixer
Publication Date: 2025.08.13 WATERS TECHNOLOGY CORP
  • EP4217729B1 patent drawingFigure 1
  • EP4217729B1 patent drawingFigure 2
  • EP4217729B1 patent drawingFigure 3

AI summary

A continuous flow mixer for use in a chromatography system includes a first channel structure located between a mixer inlet and a mixer outlet. The first channel structure includes a first inlet branch, a second inlet branch, a plurality of outlet branches including at least a first outlet branch and a second outlet branch, a first plurality of branches splitting from the first inlet branch, each branch of the first plurality of branches connected to a different of the plurality of outlet branches, and a second plurality of branches splitting from the second inlet branch, each branch of the second plurality of branches connected to a different of the plurality of outlet branches. At least two branches of the first and second plurality of branches that are connected to the first outlet branch are offset in fluid residence time through the at least two branches.