Continuous Helical Ion Guide for Mass Spectrometers

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Solution Overview

Problem

Existing mass spectrometers face challenges in efficiently transmitting ions through ion guides due to discontinuities in RF fields and geometric mismatches, leading to ion loss and reduced gas conductance.

Innovation Solution

A mass spectrometer design featuring a continuous ion guide with helically wound electrodes, transitioning from a section with variable radial diameter to one with constant radial diameter, ensuring uninterrupted RF confining fields and enhanced gas conductance, produced using methods such as winding or extrusion techniques.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If discontinuous RF fields are used in ion guides, then device complexity is reduced, but ion transmission efficiency deteriorates due to ion loss at discontinuities

Engineering Contradiction:
Improveion guide structureVSAvoidion transmission efficiency
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent applies continuous helically wound electrodes that generate uninterrupted RF fields along the ion guide axis. This eliminates discontinuities in the confining field that would otherwise cause ion loss, while the helical configuration maintains relatively simple device construction. The continuous nature of the electrodes ensures consistent ion confinement throughout the transition section.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The helical winding of electrodes creates a curved, three-dimensional configuration that provides continuous radial confinement of ions. The helical shape allows the electrodes to wrap around the ion beam path, maintaining confining fields in all radial directions while progressing continuously along the axial direction, thus eliminating field discontinuities.

Inventive Principle:
Principle #14Spheroidality (Curvature)

2Adaptability or versatility

If ion guide transitions between different pressure regimes, then mass spectrometer functionality is improved, but gas conductance deteriorates due to geometric mismatches

Engineering Contradiction:
Improvepressure regime compatibilityVSAvoidgas conductance
Core Design Contradiction:
Adaptability or versatilityVSQuantity of substance

Solution Approach 1:

The patent implements a transition section with specifically tailored variable radial diameter that is optimized for the pressure transition zone. This local modification allows the ion guide to adapt to different pressure regimes at the transition point while maintaining optimal gas conductance, without requiring changes to the entire ion guide structure.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The radial diameter of the ion guide is varied continuously along the transition section to optimize gas conductance during pressure regime changes. By adjusting this geometric parameter locally in the transition zone, the system maintains efficient gas flow and ion transmission across different pressure conditions.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If helically wound electrodes with variable radial diameter are used, then ion beam collimation is improved, but manufacturing complexity increases

Engineering Contradiction:
Improveion beam collimationVSAvoidelectrode fabrication
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The helical winding provides a natural three-dimensional curve that achieves ion beam collimation through continuous radial confinement. The helical geometry inherently creates the desired field distribution for collimation while being manufacturable using standard winding techniques, avoiding the need for complex precision machining of variable diameter components.

Inventive Principle:
Principle #14Spheroidality (Curvature)

Solution Approach 2:

The patent employs winding or extrusion techniques that are analogous to pneumatic and hydraulic forming methods. These techniques allow the electrodes to be shaped into the desired helical configuration with variable radial diameter through controlled material deposition or forming processes, simplifying manufacturing while achieving precise geometric requirements for ion beam collimation.

Inventive Principle:
Principle #29Pneumatics and hydraulics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This design facilitates unhindered ion propagation and increased gas conductance, reducing ion losses and enabling efficient transmission across different pressure regimes without detectable losses, while maintaining geometric acceptance and collimation of the ion beam.

Implementation Method 1

an ion guide with a plurality of electrodes that are supplied with a radio frequency voltage to radially confine ions

Methodology Applied
Scientific EffectRadio frequency field: Electromagnetic Induction

Implementation Method 2

the electrodes extend from the first section to the second section continuously, ensuring uninterrupted RF confining fields

Methodology Applied
Scientific EffectRF confining field: Electromagnetic Induction

Data Source

PatentEP3264443B1Mass spectrometer comprising a radio frequency ion guide having continuous electrodes
Publication Date: 2020.03.11 BRUKER SCIENTIFIC LLC
  • EP3264443B1 patent drawingFigure 1~3
  • EP3264443B1 patent drawingFigure 4~5
  • EP3264443B1 patent drawingFigure 6~7

AI summary

The invention relates to a mass spectrometer, comprising an ion guide having a plurality of electrodes that are supplied with a radio frequency voltage to facilitate radial confinement of ions in an internal volume defined by inward facing surfaces of the electrodes, the internal volume including a first section having a variable radial diameter along a longitudinal axis of the ion guide, in which the electrodes are helically wound, and an adjacent second section having a substantially constant radial diameter along the longitudinal axis, wherein the electrodes extend from the first section to the second section continuously. The continuous nature of the ion guide electrodes facilitates in particular unhindered axial propagation of ions through the assembly and prevents ion losses during their transmission through different compartments of the mass spectrometer.