Controllable High Flow Concrete Mix Design

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Solution Overview

Problem

Existing concrete mix designs face challenges with high fluidity leading to instability and segregation, particularly in self-consolidating concrete (SCC), which requires high cement content and fine aggregate, resulting in excessive heat generation, shrinkage, and difficulty in maintaining consistency and flow control.

Innovation Solution

A concrete composition with a high stone content and low cement content, utilizing two polycarboxylate comb polymers and specific viscosity modifying agents to achieve controlled slump flow and reduce segregation risk, similar to ready-mix concrete (RMC) characteristics, while maintaining high fluidity and flowability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of stationary object

If the dosage of dispersant is increased to achieve longer slump life, then slump retention is improved, but initial fluidity increases to the point where concrete mix becomes unstable and severe segregation occurs

Engineering Contradiction:
Improveslump lifeVSAvoidmix stability
Core Design Contradiction:
Duration of action of stationary objectVSStability of the object's composition

Solution Approach 1:

The invention changes the chemical parameters of the dispersant by using polycarboxylate comb polymers with specific molecular structures (comb-shaped architecture with pendant side chains) rather than conventional linear polymers. This structural parameter change allows achieving longer slump life without excessive dosage, thereby maintaining mix stability while avoiding severe segregation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite admixture systems combining polycarboxylate comb polymers with specific viscosity modifying agents (such as cellulose ethers or starch derivatives). This composite approach allows the dispersant to provide effective dispersion at lower dosages while the VMA maintains viscosity and prevents segregation, thus resolving the contradiction between slump retention and stability.

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If excessive dosage of dispersant is used to achieve longer slump life, then slump retention is improved, but setting time is extended undesirably

Engineering Contradiction:
Improveslump lifeVSAvoidsetting time
Core Design Contradiction:
Duration of action of stationary objectVSLoss of time

Solution Approach 1:

The polycarboxylate comb polymer structure changes the dosage parameter required for effective dispersion. The comb-shaped molecular architecture provides more efficient cement particle coverage per unit mass, allowing lower dosages that do not excessively interfere with cement hydration, thus avoiding extended setting times while still achieving desired slump retention.

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If SCC contains high content of fine material to produce stable mixture, then segregation resistance is improved, but cement content and pozzolan content must be increased leading to excessive heat generation and shrinkage

Engineering Contradiction:
Improvesegregation resistanceVSAvoidheat generation and shrinkage
Core Design Contradiction:
Stability of the object's compositionVSObject-generated harmful factors

Solution Approach 1:

The invention extracts the fine material requirement from the SCC system by using polycarboxylate comb polymers that provide effective dispersion and stability without needing excessive fine particles. The comb polymer structure creates a protective layer around aggregates, allowing coarser aggregate gradations and lower cement contents while maintaining segregation resistance.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the aggregate size distribution parameter by allowing coarser maximum aggregate sizes and adjusting the gradation curve to reduce fine material content. Combined with the specialized dispersant, this parameter change reduces cement content requirements while maintaining mix stability and segregation resistance.

Inventive Principle:
Principle #35Parameter changes

4Ease of operation

If SCC flows like water to achieve self-consolidation, then ease of placement is improved, but formwork requirements become more robust and water-tight increasing complexity

Engineering Contradiction:
Improveease of placementVSAvoidformwork requirements
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The invention changes the rheological parameters of the concrete by using polycarboxylate comb polymers that provide controlled flow characteristics. The dispersant creates a balance between yield stress and plastic viscosity, allowing the concrete to flow adequately for placement while maintaining enough body to not require perfectly level forms or excessively robust water-tight formwork systems.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a concrete with enhanced consistency and flow that is controllable, reduces cement requirements, decreases shrinkage and heat generation, and lowers the carbon footprint, while maintaining stability and minimizing segregation risks.

Implementation Method 1

at least two cement dispersant polycarboxylate comb polymers

Methodology Applied
Scientific EffectElectrostatic repulsion: Ion Repulsion/Attraction

Implementation Method 2

polycarboxylate comb polymer cement dispersants

Methodology Applied
Scientific EffectSteric hindrance:

Implementation Method 3

particular viscosity modifying agents

Methodology Applied
Scientific EffectPolymer chain entanglement:

Implementation Method 4

viscosity modifying agents

Methodology Applied
Scientific EffectHydrogen bonding:

Implementation Method 5

aggregate particles will tend to sink and water and cement will float to the surface

Methodology Applied
Scientific EffectGravitational settling: Gravitation

Data Source

PatentUS11352301B2Controllable high flow concrete
Publication Date: 2022.06.07 GCP APPLIED TECHNOLOGIES INC
  • US11352301B2 patent drawing
  • US11352301B2 patent drawing
  • US11352301B2 patent drawing

AI summary

The present invention relates to very high workable yet controllable concrete mix design, admixture composition, and process for placing concrete. The mix design relates to particular aggregate/cement ratios and types which are characteristic of ready mix concrete (RMC), which provide high fluidity reminiscent of self-consolidating concrete (SCC), and which provides advantages over both RMC and SCC in terms of ease and speed in placement and finishability at the construction site placement zone, regardless of whether into a horizontal formwork (e.g., for slabs, floors) or into vertical formwork (e.g., for blocks, walls, columns, etc.), without loss of control and without generating high risks of segregation even when small amounts of water are added at the size to facilitate finishing of the concrete surface. An inventive admixture combination which enables this unique design involves two different polycarboxylate comb polymers in combination with two specific viscosity modifying agents, and this combination provides highly workable concrete to be placed in a controlled, efficient manner.