Cooling Plate Adhesive Composition for Coolant-Resistant Bonding

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Solution Overview

Problem

Cooling plate assemblies for vehicle batteries face premature failure due to degradation of adhesives by coolant, leading to potential damage and reduced performance over time.

Innovation Solution

Incorporating epoxy-functional hydrolyzable organosilane in the adhesive to form crosslinks, which enhances the adhesive's resistance to coolant degradation and maintains structural integrity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If adhesive bonding is used to join cooling plate components, then environmental friendliness and suitability for large components are improved, but adhesive strength deteriorates over time due to coolant degradation

Engineering Contradiction:
Improveease of manufactureVSAvoidadhesive strength
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the adhesive by incorporating hydrolyzable organosilane compounds (such as γ-glycidoxypropyltrimethoxysilane) that undergo hydrolysis and condensation reactions to form siloxane crosslinks. This transforms the adhesive from a simple epoxy formulation to one that dynamically adapts its molecular structure in response to coolant exposure, maintaining bond strength despite prolonged immersion in degrading environments.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite adhesive system combining epoxy resin with hydrolyzable organosilane compounds. This composite formulation leverages the strong initial bonding of epoxy while adding the self-repairing crosslinking capability of silane chemistry, resulting in an adhesive that exhibits both high initial strength and long-term durability against coolant degradation.

Inventive Principle:
Principle #40Composite materials

2Strength

If conventional adhesive is used in cooling plate assembly, then initial bonding strength is achieved, but adhesive strength drops over time due to coolant attack

Engineering Contradiction:
Improveadhesive strengthVSAvoidservice life
Core Design Contradiction:
StrengthVSDuration of action of stationary object

Solution Approach 1:

The patent incorporates hydrolyzable organosilane groups into the adhesive formulation before application. These groups are pre-positioned to undergo hydrolysis and condensation reactions when exposed to moisture in the coolant environment, forming additional siloxane crosslinks that compensate for adhesive strength loss over time. The preliminary inclusion of these reactive groups enables the adhesive to self-reinforce during service.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The adhesive system performs self-service by utilizing the coolant environment itself (specifically the moisture content) to trigger hydrolysis and condensation reactions of the organosilane groups. This self-reinforcing mechanism automatically compensates for degradation without requiring external intervention, maintaining bonding strength throughout the service life of the cooling plate assembly.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of epoxy-functional hydrolyzable organosilane in the adhesive composition improves the durability and longevity of cooling plate assemblies by compensating for strength drops caused by coolant exposure, ensuring reliable heat management for vehicle batteries.

Implementation Method 1

hydrolysis and condensation of the silane groups to form new crosslinks compensate for any adhesive strength drop due to coolant attack on the adhesive

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 2

hydrolysis and condensation of the silane groups to form new crosslinks compensate for any adhesive strength drop due to coolant attack on the adhesive

Methodology Applied
Scientific EffectCondensation: Condensation

Data Source

PatentUS20240409784A1Cooling plate assembly, method of making the same, and curable composition
Publication Date: 2024.12.12 3M INNOVATIVE PROPERTIES CO
  • US20240409784A1 patent drawing
  • US20240409784A1 patent drawing
  • US20240409784A1 patent drawing

AI summary

A cooling plate assembly comprises at least two component plates bonded together by an adhesive. The adhesive and the at least two component plates collectively define at least one fluid conduit having an inlet and an outlet. The adhesive comprises an epoxy-functional hydrolyzable organosilane compound. A method of making the cooling plate assembly, and a curable composition useful for making the adhesive are also disclosed.