Cooling Transfer Slurry Between Polyolefin Reactors

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Solution Overview

Problem

In polyolefin production, maintaining effective temperature control across multiple polymerization reactors is challenging due to variations in reactor feedstocks and reaction kinetics, leading to inefficiencies in heat removal and increased costs, which can impact production rates and product quality.

Innovation Solution

A polyolefin production system that includes a first reactor producing a polyolefin discharge, a heat exchanger to cool the transfer slurry, and a second reactor receiving the cooled slurry to produce a combined polyolefin product, with a temperature difference of at least 3° F between the reactor discharges, enhancing heat transfer and production capacity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If multiple polymerization reactors are operated in series without intermediate cooling, then the system complexity is reduced, but temperature control effectiveness deteriorates leading to reduced productivity

Engineering Contradiction:
Improveproduction rateVSAvoidtemperature control
Core Design Contradiction:
ProductivityVSTemperature

Solution Approach 1:

The patent divides the polymerization process into multiple separate reactor stages (first reactor, second reactor, third reactor) with intermediate cooling zones between them. This segmentation allows temperature control to be applied at discrete points between reactors, preventing thermal accumulation while maintaining overall process continuity and productivity.

Inventive Principle:
Principle #1Segmentation

2Loss of energy

If heat exchangers are added between reactors to cool transfer slurry, then heat removal capability increases, but device complexity increases

Engineering Contradiction:
Improveheat removal capabilityVSAvoidsystem complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The patent implements cooling zones that pre-cool the transfer slurry between reactor stages before it enters the next reactor. This preliminary cooling action removes heat of polymerization proactively, preventing temperature runaway and reducing the thermal load on subsequent reactors, thereby improving overall heat removal capability.

Inventive Principle:
Principle #10Preliminary action

3Productivity

If transfer slurry is cooled between reactors, then heat transfer efficiency increases, but manufacturing complexity increases

Engineering Contradiction:
Improveheat transfer efficiencyVSAvoidmanufacturing complexity
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent changes the temperature parameter of the transfer slurry between reactor stages by implementing controlled cooling zones. The slurry is cooled from the higher temperature of the first reactor to a lower temperature before entering the second reactor, optimizing heat transfer efficiency and polymerization control without requiring fundamental process redesign.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach increases heat removal capability in downstream reactors, leading to higher production rates and reduced coolant system costs, while maintaining effective temperature control and product quality.

Implementation Method 1

a heat exchanger to cool the transfer slurry

Methodology Applied
Scientific EffectHeat transfer: Heat Exchanger

Data Source

PatentUS10646845B2Cooling between multiple polyolefin polymerization reactors
Publication Date: 2020.05.12 CHEVRON PHILLIPS CHEMICAL COMPANY LP
  • US10646845B2 patent drawing
  • US10646845B2 patent drawing
  • US10646845B2 patent drawing

AI summary

A system and method for a first reactor to produce a transfer slurry having a first polyolefin polymerized in the first reactor, a heat-removal zone to remove heat from the transfer slurry, and a second reactor to receive the transfer slurry cooled by the heat-removal zone, the second reactor to produce a product slurry having a product polyolefin which includes the first polyolefin and a second polyolefin polymerized in the second reactor.