Copolyamide Hot-Melt Yarn Elasticity and Melting Point Control
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Solution Overview
Problem
Current copolyamide resins used in hot-melt yarns, such as nylon 66 and nylon 6, exhibit low elasticity and high melting points, which do not meet the requirements for special materials like flying woven fabrics.
Innovation Solution
A method for preparing copolyamide resin involving specific raw materials and processes, including the use of sulfur-containing compounds and ethylene oxide to create elasticity regulators, which are then integrated into the resin production to lower the melting point and enhance elasticity.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Temperature
If conventional copolyamide resins (nylon 66, nylon 6) are used in hot-melt yarns, then the yarns achieve good thermal bonding properties and stable processability, but the materials exhibit low elasticity and high melting points that do not meet special material requirements
Solution Approach 1:
The patent creates a composite polymer system by reacting polyamide precursor polymers with cyclic carbonates to form copolyamide resin containing both polyamide segments and cyclic carbonate segments. This composite structure at the molecular level allows the material to simultaneously achieve low melting point (from cyclic carbonate segments) and high elasticity (from the flexible chain structure introduced by the cyclic carbonate groups), resolving the contradiction between melting point and elasticity.
Solution Approach 2:
The patent changes the chemical composition parameters of the copolyamide resin by controlling the molar ratio of cyclic carbonate to polyamide precursor polymer (1:4 to 1:20), and by selecting different polyamide types (PA6, PA66, PA11, PA12) and cyclic carbonates (trimethylene carbonate, ethylene carbonate). This parameter optimization enables precise control over both melting point and elasticity, achieving the desired balance between these two properties.
2Stability of the object's composition
If copolyamide resin with lowered melting point is prepared using cyclic carbonates and polyamide precursors, then elasticity is improved, but the production process complexity increases
Solution Approach 1:
The patent divides the polymerization process into two distinct stages: first synthesizing polyamide precursor polymers with specific molecular weights and end groups, then reacting these precursors with cyclic carbonates in a separate step. This segmentation allows each stage to be optimized independently, simplifying process control and reducing overall production complexity despite the multi-step nature of the process.
Solution Approach 2:
The patent uses polyamide precursor polymers as intermediaries that contain reactive end groups (carboxyl or amino groups) which then react with cyclic carbonates. This intermediary approach enables the controlled introduction of cyclic carbonate segments into the polyamide chain, making the complex copolymerization process more manageable and easier to control compared to direct copolymerization.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The resulting copolyamide resin and hot-melt yarns exhibit improved elasticity and a lower melting point, with the yarns having good elasticity and a low bonding temperature, addressing the limitations of existing materials.
Implementation Method 1
adding propylene oxide into a reactor with a sulfur-containing compound with a molar ratio of propylene oxide to the sulfur-containing compound at 2-20:1, to react for 6-10h at a reaction temperature of 120-170°C and a reaction pressure of 0.4-1.2MPa
Implementation Method 2
introducing ethylene oxide into a reactor with the elasticity regulator A with a molar ratio of ethylene oxide to the sulfur-containing compound at 2-20:1, to react for 5-8h at a reaction temperature of 100-150°C and a pressure of 0.4 -1.2MPa
Implementation Method 3
heating the copolyamide resin in an extruder to melt to obtain a spinning dope
Data Source
AI summary
The present invention discloses a method for preparing copolyamide resin and copolyamide hot-melt yarn. By introducing the elasticity regulator, the method can ensure that the melting point of the copolyamide resin is lowered and its elasticity is increased, and the copolyamide hot-melt yarn herein has the advantages of good elastiuciuty and low bonding temperature.