Copolymer Alignment Agent for LCD Voltage Holding and Afterimage Reduction

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Solution Overview

Problem

Conventional liquid crystal display devices face challenges in achieving uniform brightness and high contrast ratios due to limitations in liquid crystal alignment agents, which affect both alignment properties and electrical properties such as afterimages and voltage holding ratios, especially under high temperatures and mechanical stress.

Innovation Solution

A copolymer is developed incorporating specific repeating units derived from imide-containing diamine and nitrogen atom-containing diamine compounds, allowing for improved liquid crystal alignment and electrical properties without the need for high-temperature heat treatments, enabling efficient light irradiation and enhanced alignment stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional liquid crystal alignment agents (polyimide, polyamide, polyester) are used, then basic alignment properties are achieved, but electrical properties (afterimage, voltage holding ratio) deteriorate under high temperature and mechanical stress

Engineering Contradiction:
Improveelectrical propertiesVSAvoidafterimage and voltage holding ratio degradation
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent modifies the chemical structure of the alignment agent by introducing specific functional groups (sulfone, carbonyl, ether linkages) and controlling molecular weight and composition ratios to simultaneously improve electrical properties and alignment performance under high temperature conditions

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite polymer structure combining multiple functional units (imide rings, sulfone groups, aromatic hydrocarbons) within a single alignment agent molecule to achieve both excellent alignment properties and electrical stability

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If monomer structure or composition is changed to improve physical/chemical properties, then alignment properties are enhanced, but manufacturing complexity increases

Engineering Contradiction:
Improvealignment uniformityVSAvoidpolymer structure complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent divides the polymer structure into distinct functional segments (imide units, sulfone units, aromatic units) with specific repeating patterns, allowing independent optimization of each segment's function while maintaining overall manufacturing feasibility

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention introduces specific functional groups at particular positions within the polymer chain (e.g., sulfone groups at regular intervals, specific aromatic hydrocarbon structures) to provide localized alignment enhancement without complicating the entire polymer structure

Inventive Principle:
Principle #3Local quality

3Stability of the object's composition

If high-temperature heat treatment is applied to improve alignment, then alignment stability is enhanced, but energy consumption and processing time increase

Engineering Contradiction:
Improvealignment stabilityVSAvoidheat treatment energy consumption
Core Design Contradiction:
Stability of the object's compositionVSUse of energy by stationary object

Solution Approach 1:

The patent replaces the mechanical/thermal alignment method (high-temperature heat treatment) with a chemical alignment mechanism inherent in the polymer structure, where the molecular architecture itself provides alignment guidance without requiring extreme thermal energy input

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The alignment agent's molecular structure contains built-in alignment-promoting features (rigid aromatic cores, directional functional groups) that automatically organize liquid crystal molecules through molecular interactions, eliminating the need for external high-temperature processing

Inventive Principle:
Principle #25Self-service

Data Source

PatentUS11345782B2Copolymer for liquid crystal alignment agent, liquid crystal alignment agent including the same, and liquid crystal alignment film and liquid crystal display device using the same
Publication Date: 2022.05.31 LG CHEM LTD
  • US11345782B2 patent drawing
  • US11345782B2 patent drawing
  • US11345782B2 patent drawing

AI summary

A polymer having excellent liquid crystal alignment and electrical properties and thus is suitable for use as a liquid crystal alignment agent, a liquid crystal alignment agent including the same, a liquid crystal alignment film formed from the liquid crystal alignment agent, and a liquid crystal display device including the liquid crystal alignment film are provided.