Block Copolymer Annealing Control Using Real-Time Swelling Feedback

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Solution Overview

Problem

The kinetics of block copolymer self-assembly for pattern formation in nanoscale device fabrication are sensitive to swelling levels, requiring precise control of thermodynamic conditions to achieve fast and efficient pattern formation.

Innovation Solution

An apparatus and method that measures swelling during solvent vapour annealing and uses temperature control means, including thermoelectric cooling modules, to optimize thermodynamic conditions for pattern formation, with optical measurement means to monitor thickness and control circuitry to adjust temperature based on swelling data.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If solvent vapour annealing is used to accelerate pattern formation, then productivity is improved, but swelling control becomes difficult leading to processing issues

Engineering Contradiction:
Improvepattern formation speedVSAvoidswelling control
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent implements real-time feedback control by measuring swelling level changes during solvent vapour annealing and using this information to dynamically adjust processing parameters. The system continuously monitors the block copolymer swelling and adjusts temperature or solvent exposure accordingly, resolving the contradiction between accelerated pattern formation and precise swelling control.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent dynamically changes processing parameters (temperature, solvent vapour concentration, exposure time) based on real-time swelling measurements. By adjusting these parameters in response to measured swelling levels, the system maintains optimal conditions for both fast pattern formation and precise swelling control.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If temperature is increased to speed up self-assembly, then productivity is improved, but swelling control becomes less precise

Engineering Contradiction:
Improveself-assembly speedVSAvoidswelling precision
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent transitions from static temperature control to dynamic temperature control that adapts in real-time based on measured swelling levels. The temperature is continuously adjusted during the self-assembly process rather than maintained at a fixed value, enabling both fast processing and precise swelling control through adaptive parameter changes.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The system uses real-time swelling measurements to provide feedback for temperature adjustment. When swelling reaches desired levels or deviates from targets, the temperature is automatically adjusted to correct the swelling, maintaining precision while enabling faster overall processing through optimized thermal history.

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables faster and more efficient pattern formation, reducing processing time and minimizing dewetting, thereby improving the efficiency of nanoscale device fabrication.

Implementation Method 1

The measurement means may comprise optical measurement means. The optical measurement means may comprise at least one of a reflectometer, an ellipsometer.

Methodology Applied
Scientific EffectOptical measurement:

Implementation Method 2

The temperature control means may comprise a thermoelectric cooling module.

Methodology Applied
Scientific EffectThermoelectric cooling: Peltier Effect

Implementation Method 3

measuring swelling of a block copolymer during solvent vapour annealing of the block copolymer

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentUS11823902B2Apparatus and method for solvent vapour annealing of a block copolymer
Publication Date: 2023.11.21 NOKIA TECHNOLOGIES OY
  • US11823902B2 patent drawing
  • US11823902B2 patent drawing
  • US11823902B2 patent drawing

AI summary

An apparatus and method which may be used for fabricating nanoscale devices are disclosed. The apparatus comprises measurement means configured to measure swelling of a block copolymer during solvent vapour annealing of the block copolymer. The apparatus also comprises temperature control means configured to receive a control signal indicative of the swelling of the block copolymer. The temperature control means can then control the temperature of the block copolymer as indicated by the control signal.