Copolymer Memristor Layer for Stable Analog Synaptic Switching

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Solution Overview

Problem

Conventional memristor devices, particularly CBRAM, face challenges in implementing reliable analog switching characteristics and symmetric synaptic properties due to the rapid formation or breaking of conductive filaments under pulse voltage, leading to inefficiencies in neuromorphic systems.

Innovation Solution

A polymer memristor device with a resistance changing layer comprising a copolymer of vinylimidazole and 1,3,5-trivinyl-1,3,5-trimethylcyclotrisiloxane, where the copolymer has varying metal ion diffusivity, is used, enabling stable synaptic properties and analog switching characteristics through a simple structure and fabrication process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If CBRAM is used to implement memristor device, then fast operation speed and high ON/OFF ratio are achieved, but reliable analog switching characteristics and symmetric synaptic properties cannot be implemented due to rapid filament formation/breaking

Engineering Contradiction:
Improveoperation speedVSAvoidanalog switching characteristics
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent changes the material parameters of the resistance changing layer from conventional CBRAM materials to a specific copolymer composition (vinylimidazole and 1,3,5-trivinyl-1,3,5-trimethylcyclotrisiloxane) with controlled metal ion diffusivity. This parameter change enables gradual filament collapse instead of rapid breaking, achieving reliable analog switching characteristics while maintaining fast operation speed and high ON/OFF ratio.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite copolymer material formed by polymerizing two different monomers (vinylimidazole and 1,3,5-trivinyl-1,3,5-trimethylcyclotrisiloxane) in specific ratios. This composite material structure provides both fast operation speed and reliable analog switching characteristics by controlling metal ion diffusion through the combined properties of the two polymer components.

Inventive Principle:
Principle #40Composite materials

2Device complexity

If conventional polymer materials are used in memristor device, then device complexity is reduced, but metal ion diffusion control and synaptic property stability are insufficient

Engineering Contradiction:
Improvestructure complexityVSAvoidsynaptic property stability
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent modifies the polymer material parameters by selecting specific monomers with different metal ion diffusivity characteristics and controlling their composition ratios. This enables precise control of metal ion diffusion rates, achieving stable synaptic properties while maintaining the simplicity of polymer-based device structure and fabrication processes.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The polymer memristor device achieves excellent and stable synaptic properties, symmetric synaptic characteristics, and improved performance uniformity, enhancing the recognition rate of neuromorphic systems by controlling metal ion diffusion effectively.

Implementation Method 1

a first polymer which is formed from the first monomer is a polymer having a property that diffusion of metal ions thereof is faster than that of a second polymer which is formed from the second monomer

Methodology Applied
Scientific EffectMetal ion diffusion: Diffusion

Data Source

PatentUS11793006B2Memristor device, method of fabricating thereof, synaptic device including memristor device and neuromorphic device including synaptic device
Publication Date: 2023.10.17 SK HYNIX INC
  • US11793006B2 patent drawing
  • US11793006B2 patent drawing
  • US11793006B2 patent drawing

AI summary

Disclosed are a memristor device, a method of fabricating the same, a synaptic device including a memristor device, and a neuromorphic device including a synaptic device. The disclosed memristor device may comprise a first electrode, a second electrode disposed to be spaced apart from the first electrode; and a resistance changing layer including a copolymer between the first electrode and the second electrode. The copolymer may be a copolymer of a first monomer and a second monomer, and the first polymer formed from the first monomer may have a property that diffusion of metal ions is faster than that of the second polymer formed from the second monomer. The second polymer may have a lower diffusivity of metal ions as compared with the first polymer. The first monomer may include vinylimidazole (VI). The second monomer may include 1,3,5-trivinyl-1,3,5-trimethylcyclotrisiloxane (V3D3). The copolymer may include p(V3D3-co-VI).