Copolymer Patterning for Vertically Aligned MOSFET Features
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Solution Overview
Problem
The scale-down of metal-oxide-semiconductor field-effect transistors (MOSFETs) in semiconductor devices leads to deterioration in operational properties, necessitating improved reliability and electrical characteristics.
Innovation Solution
A method of manufacturing semiconductor devices involving the formation of a copolymer layer with different polymers, including a first and second polymer, and performing an annealing process to align these polymers vertically, enhancing the reliability and electrical characteristics through directed self-assembly (DSA) without etching the photoresist patterns.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Area of moving object
If MOSFETs are scaled down to meet increasing demand for small pattern size, then pattern size is reduced, but operational properties deteriorate
Solution Approach 1:
The patent introduces a vertical dimension by forming a three-dimensional channel structure where the channel extends vertically through multiple levels. This 3D architecture allows continued scaling of the device footprint while maintaining effective channel length and improving operational properties through enhanced electric field control and carrier transport in the vertical direction.
Solution Approach 2:
The patent employs composite material structures including stacked semiconductor layers with different materials (e.g., SiGe source/drain regions with silicon channel, or III-V semiconductor layers) to maintain carrier mobility and electrical characteristics despite device scaling. The composite structure enables optimization of different regions for specific functions while keeping the overall device size reduced.
2Manufacturing precision
If copolymer layer is formed with different polymers and annealed to align vertically, then alignment and stability of patterns are improved, but process complexity increases
Solution Approach 1:
The patent utilizes self-service by employing block copolymer materials that automatically phase-separate and self-align into vertical cylindrical structures during the annealing process. The thermodynamic driving force of microphase separation in block copolymers causes the polymers to spontaneously organize into the desired vertical alignment without requiring external guidance patterns or complex alignment procedures, thereby achieving high manufacturing precision through material self-organization.
Solution Approach 2:
The patent exploits phase transitions by heating the block copolymer layer above its glass transition temperature during annealing. This phase transition enables the polymer chains to become mobile and reorganize into the thermodynamically stable vertical cylindrical morphology. The phase transition process drives the spontaneous alignment and ordering of the copolymer domains, achieving precise vertical patterns while using a relatively simple thermal processing step.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The method improves the alignment and stability of patterns, leading to enhanced electrical characteristics and reliability of semiconductor devices by aligning polymers in a vertical direction during the annealing process, allowing for finer patterns without etching the photoresist patterns.
Implementation Method 1
performing an annealing process on the copolymer layer, wherein the copolymer layer includes a first polymer and a second polymer different from the first polymer
Implementation Method 2
the phase-separating of the copolymer layer includes aligning the first polymer in a vertical direction on the first polymer pattern
Implementation Method 3
irradiating the photoresist layer with extreme ultraviolet light to form a photoresist pattern
Data Source
AI summary
A method of manufacturing includes forming a first anti-reflection pattern on a substrate, forming a photoresist pattern on the first anti-reflection pattern, forming a first polymer pattern on the photoresist pattern, forming a copolymer layer on the first anti-reflection pattern and the first polymer pattern, and performing an annealing process on the copolymer layer, wherein the copolymer layer includes a first polymer and a second polymer different from the first polymer, and the first polymer pattern includes the first polymer.


