Copolymer Patterning for Vertically Aligned MOSFET Features

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

The scale-down of metal-oxide-semiconductor field-effect transistors (MOSFETs) in semiconductor devices leads to deterioration in operational properties, necessitating improved reliability and electrical characteristics.

Innovation Solution

A method of manufacturing semiconductor devices involving the formation of a copolymer layer with different polymers, including a first and second polymer, and performing an annealing process to align these polymers vertically, enhancing the reliability and electrical characteristics through directed self-assembly (DSA) without etching the photoresist patterns.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Area of moving object

If MOSFETs are scaled down to meet increasing demand for small pattern size, then pattern size is reduced, but operational properties deteriorate

Engineering Contradiction:
Improvepattern sizeVSAvoidoperational properties
Core Design Contradiction:
Area of moving objectVSReliability

Solution Approach 1:

The patent introduces a vertical dimension by forming a three-dimensional channel structure where the channel extends vertically through multiple levels. This 3D architecture allows continued scaling of the device footprint while maintaining effective channel length and improving operational properties through enhanced electric field control and carrier transport in the vertical direction.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Solution Approach 2:

The patent employs composite material structures including stacked semiconductor layers with different materials (e.g., SiGe source/drain regions with silicon channel, or III-V semiconductor layers) to maintain carrier mobility and electrical characteristics despite device scaling. The composite structure enables optimization of different regions for specific functions while keeping the overall device size reduced.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If copolymer layer is formed with different polymers and annealed to align vertically, then alignment and stability of patterns are improved, but process complexity increases

Engineering Contradiction:
Improvealignment of patternsVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent utilizes self-service by employing block copolymer materials that automatically phase-separate and self-align into vertical cylindrical structures during the annealing process. The thermodynamic driving force of microphase separation in block copolymers causes the polymers to spontaneously organize into the desired vertical alignment without requiring external guidance patterns or complex alignment procedures, thereby achieving high manufacturing precision through material self-organization.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent exploits phase transitions by heating the block copolymer layer above its glass transition temperature during annealing. This phase transition enables the polymer chains to become mobile and reorganize into the thermodynamically stable vertical cylindrical morphology. The phase transition process drives the spontaneous alignment and ordering of the copolymer domains, achieving precise vertical patterns while using a relatively simple thermal processing step.

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method improves the alignment and stability of patterns, leading to enhanced electrical characteristics and reliability of semiconductor devices by aligning polymers in a vertical direction during the annealing process, allowing for finer patterns without etching the photoresist patterns.

Implementation Method 1

performing an annealing process on the copolymer layer, wherein the copolymer layer includes a first polymer and a second polymer different from the first polymer

Methodology Applied
Scientific EffectPhase separation: Phase Change

Implementation Method 2

the phase-separating of the copolymer layer includes aligning the first polymer in a vertical direction on the first polymer pattern

Methodology Applied
Scientific EffectDirected self-assembly: Self-Assembly

Implementation Method 3

irradiating the photoresist layer with extreme ultraviolet light to form a photoresist pattern

Methodology Applied
Scientific EffectPhotoresist exposure: Photopolymerisation

Data Source

PatentUS20250226220A1Semiconductor device and method of manufacturing the same
Publication Date: 2025.07.10 SAMSUNG ELECTRONICS CO LTD
  • US20250226220A1 patent drawing
  • US20250226220A1 patent drawing
  • US20250226220A1 patent drawing

AI summary

A method of manufacturing includes forming a first anti-reflection pattern on a substrate, forming a photoresist pattern on the first anti-reflection pattern, forming a first polymer pattern on the photoresist pattern, forming a copolymer layer on the first anti-reflection pattern and the first polymer pattern, and performing an annealing process on the copolymer layer, wherein the copolymer layer includes a first polymer and a second polymer different from the first polymer, and the first polymer pattern includes the first polymer.